AaminaNaaz Y, Rajkumar K, Thirumurugan S, Anbalagan K, SubbiahPandi A
Department of Physics, Presidency College (Autonomous), Chennai 600 005, India.
Department of Chemistry, Pondicherry University, Pondicherry 605 014, India.
IUCrdata. 2020 May 12;5(Pt 5):x200618. doi: 10.1107/S2414314620006185. eCollection 2020 May.
The title complex, [Zn(CHN)][ZnCl], exists as discrete ions. The [Zn(CHN)] cation exhibits a distorted octa-hedral shape. In the [ZnCl] anion, the Zn atom is in an almost regular tetra-hedral environment. The crystal packing is consolidated by N-H⋯Cl and C-H⋯Cl hydrogen bonds.
标题配合物[Zn(CHN)][ZnCl]以离散离子形式存在。[Zn(CHN)]阳离子呈现出扭曲的八面体形状。在[ZnCl]阴离子中,锌原子处于几乎规则的四面体环境中。晶体堆积通过N-H⋯Cl和C-H⋯Cl氢键得以巩固。