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双（N，N，N'，N'-四甲基胍鎓）四氯合铜酸盐（II）的晶体结构

Crystal structure of bis-(N,N,N',N'-tetra-methyl-guanidinium) tetra-chlorido-cuprate(II).

作者信息

Ndiaye Mamadou, Samb Abdoulaye, Diop Libasse, Maris Thierry

机构信息

Laboratoire des Produits Naturels, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

出版信息

Acta Crystallogr E Crystallogr Commun. 2016 Jun 24;72(Pt 7):1047-9. doi: 10.1107/S2056989016010161. eCollection 2016 Jul 1.

DOI:10.1107/S2056989016010161
PMID:27555960
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4992935/
Abstract

In the structure of the title salt, (C5H14N3)2[CuCl4], the Cu(II) atom in the anion lies on a twofold rotation axis. The tetra-chlorido-cuprate(II) anion adopts a flattened tetra-hedral coordination environment and inter-acts electrostatically with the tetra-methyl-guanidinium cation. The crystal packing is additionally consolidated through N-H⋯Cl and C-H⋯Cl hydrogen bonds, resulting in a three-dimensional network structure.

摘要

在标题盐（C5H14N3）2[CuCl4]的结构中，阴离子中的Cu（II）原子位于一个二重旋转轴上。四氯合铜（II）阴离子采用扁平的四面体配位环境，并与四甲基胍阳离子发生静电相互作用。晶体堆积还通过N-H⋯Cl和C-H⋯Cl氢键得到巩固，形成三维网络结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4f8/4992935/b5c42e4a2d64/e-72-01047-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4f8/4992935/bb2679a71752/e-72-01047-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4f8/4992935/b5c42e4a2d64/e-72-01047-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4f8/4992935/bb2679a71752/e-72-01047-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4f8/4992935/b5c42e4a2d64/e-72-01047-fig2.jpg

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本文引用的文献

1
The Cambridge Structural Database.剑桥结构数据库。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. doi: 10.1107/S2052520616003954. Epub 2016 Apr 1.
2
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Acta Crystallogr E Crystallogr Commun. 2016 Jan 1;72(Pt 1):40-3. doi: 10.1107/S2056989015023348.
3
Crystal structure of catena-poly[N,N,N',N'-tetra-methyl-guanidinium [(chlorido-cadmate)-di-μ-chlorido]].
链状聚[N,N,N',N'-四甲基胍鎓][(氯镉酸根)-二-μ-氯]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jan 1;72(Pt 1):1-3. doi: 10.1107/S2056989015020836.
4
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination.用于单晶结构测定的银和钼微焦点X射线源的比较。
J Appl Crystallogr. 2015 Jan 30;48(Pt 1):3-10. doi: 10.1107/S1600576714022985. eCollection 2015 Feb 1.
5
New organically templated thiocyanatocadmates and chlorocuprate(II): synthesis and structural characterization.新型有机模板硫氰酸镉盐和氯铜酸盐（II）：合成与结构表征
Dalton Trans. 2015 Jul 7;44(25):11470-81. doi: 10.1039/c5dt01355k.
6
The square-planar to flattened-tetrahedral CuX4(2-) (X = Cl, Br) structural phase transition in 1,2,6-trimethylpyridinium salts.1,2,6-三甲基吡啶鎓盐中平面正方形到扁平四面体的CuX4(2-)(X = Cl, Br)结构相变
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2015 Feb;71(Pt 1):48-60. doi: 10.1107/S205252061402664X. Epub 2015 Feb 1.
7
Reversible uptake of COS, CS2, and SO2: ionic liquids with O-alkylxanthate, O-alkylthiocarbonyl, and O-alkylsulfite anions.COS、CS2和SO2的可逆吸收：含O-烷基黄原酸根、O-烷基硫代羰基和O-烷基亚硫酸根阴离子的离子液体。
Chemistry. 2009 Aug 3;15(31):7619-27. doi: 10.1002/chem.200802602.
8
Structural variation in copper(I) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, tau4.含吡啶甲基酰胺配体的一价铜配合物的结构变异：用新的四配位几何指数τ4进行结构分析
Dalton Trans. 2007 Mar 7(9):955-64. doi: 10.1039/b617136b. Epub 2007 Jan 29.