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()-1-(2-羟基-4,6-二甲氧基苯基)-3-(萘-1-基)丙-2-烯-1-酮

()-1-(2-Hy-droxy-4,6-di-meth-oxy-phen-yl)-3-(naph-thalen-1-yl)prop-2-en-1-one.

作者信息

Koh Dongsoo

机构信息

Department of Applied Chemistry, Dongduk Women's University, Seoul, 02748, Republic of Korea.

出版信息

IUCrdata. 2022 Sep 27;7(Pt 9):x220932. doi: 10.1107/S2414314622009324. eCollection 2022 Sep.

DOI:10.1107/S2414314622009324
PMID:36337459
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9635433/
Abstract

In the title compound, CHO, the relative conformation of the C=C and C=O double bonds in the central enone group is ; there is a configuration about the C=C bond. The dihedral angle formed by the naphthalene ring system and the benzene ring is 16.80 (2)°. The meth-oxy groups at the and positions of the benzene ring are tilted to the ring by 169.8 (1) and 174.5 (1)°, respectively. The hy-droxy group in the benzene ring participates in an intra-molecular O-H⋯O hydrogen bond. In the crystal, C-H⋯O inter-actions link mol-ecules into linear chains along the -axis direction.

摘要

在标题化合物CHO中,中央烯酮基团中C=C和C=O双键的相对构象为 ;C=C键存在 构型。萘环体系与苯环形成的二面角为16.80 (2)°。苯环 和 位的甲氧基分别向环倾斜169.8 (1)°和174.5 (1)°。苯环中的羟基参与分子内O-H⋯O氢键。在晶体中,C-H⋯O相互作用将分子沿 轴方向连接成线性链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f08a/9635433/c7844acbf127/x-07-x220932-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f08a/9635433/5b9b861aee7a/x-07-x220932-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f08a/9635433/c7844acbf127/x-07-x220932-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f08a/9635433/5b9b861aee7a/x-07-x220932-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f08a/9635433/c7844acbf127/x-07-x220932-fig2.jpg

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