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-（2a，2a′，3a，3a′，5a，6a）-2a-烯丙基-2,4-二氯-2a，2a，3a，5a，6，6a-六氢-3a，3-二氧杂二环戊二烯并[，]戊搭烯-3a-醇

-(2a,2a ,3a,3a ,5a,6a)-2a-Allyl-2,4-di-chloro-2a,2a,3a,5a,6,6a-hexa-hydro-3a-3-oxadi-cyclo-penta-[,]penta-len-3a-ol.

作者信息

Kotha Sambasivarao, Ansari Saima, Gupta Naveen Kumar

机构信息

Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai - 400076, India.

出版信息

IUCrdata. 2021 Dec 16;6(Pt 12):x211260. doi: 10.1107/S2414314621012608. eCollection 2021 Dec.

DOI:10.1107/S2414314621012608
PMID:36337590
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462309/
Abstract

The title racemic triquinane, CHClO, is composed of four five-membered rings, one of which is a tetra-hydro-furan ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a configuration. In the crystal, the mol-ecules are linked by pairwise O-H⋯O hydrogen bonds, generating inversion dimers featuring (8) loops.

摘要

标题化合物外消旋三环癸烷（CHClO）由四个五元环组成，其中一个是四氢呋喃环，其一侧连接一个烯丙基，另一侧连接一个羟基。三环癸烷单元的核心具有 构型。在晶体中，分子通过成对的O-H⋯O氢键相连，形成具有 (8) 环的反演二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/75a2/9462309/ef9ab92c8a48/x-06-x211260-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/75a2/9462309/48710c47d62f/x-06-x211260-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/75a2/9462309/6486142686e9/x-06-x211260-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/75a2/9462309/ef9ab92c8a48/x-06-x211260-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/75a2/9462309/48710c47d62f/x-06-x211260-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/75a2/9462309/6486142686e9/x-06-x211260-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/75a2/9462309/ef9ab92c8a48/x-06-x211260-fig3.jpg

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