Shraddha K N, Devika S, Begum Noor Shahina
Department of Studies in Chemistry, Bangalore University, Jnana Bharathi Campus, Bangalore 560 056, Karnataka, India.
IUCrdata. 2020 Jan 3;5(Pt 1):x191690. doi: 10.1107/S2414314619016900. eCollection 2020 Jan.
In the title compound, CHClNO, the 5-chloro-phenol ring and the imidazole ring are nearly coplanar, with a dihedral angle of 15.76 (9)° between them. The ethyl-phenyl ring and the two phenyl rings subtend angles of 71.09 (7), 43.95 (5) and 36.53 (9)°, respectively, with the imidazole plane. An intra-molecular O-H⋯N hydrogen bond supports the mol-ecular conformation, and an inter-molecular C-H⋯O inter-action, originating from an -phenyl H atom, stabilizes the packing arrangement. In addition, a weak C-H⋯π inter-action, also involving an -phenyl H atom, is observed.
在标题化合物CHClNO中,5-氯苯酚环和咪唑环几乎共面,它们之间的二面角为15.76 (9)°。乙基苯环和两个苯环与咪唑平面分别呈71.09 (7)°、43.95 (5)°和36.53 (9)°的夹角。分子内的O-H⋯N氢键支撑着分子构象,源自苯环上一个H原子的分子间C-H⋯O相互作用稳定了堆积排列。此外,还观察到一个同样涉及苯环上一个H原子的弱C-H⋯π相互作用。