6-（3,4-二氟苯基）-7,8,13,14-四氢二苯并[α，h]菲啶
6-(3,4-Di-fluoro-phen-yl)-7,8,13,14-tetra-hydro-dibenzo[,]phenanthridine.
作者信息
Fang Yiwen, Liu Bingbing, Jia Zhixiang
机构信息
Department of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of China.
Department of Chemistry, Yancheng Teachers College, Yancheng, Jiangsu, 224002, People's Republic of China.
出版信息
IUCrdata. 2020 Sep 11;5(Pt 9):x201241. doi: 10.1107/S2414314620012419. eCollection 2020 Sep.
Abstract
In the title compound, CHFN, the five-fused-ring system is highly puckered and the dihedral angle between the central pyridine ring and pendant di-fluoro-benzene ring is 45.12 (12)°. In the crystal, inversion dimers linked by pairwise weak C-H⋯N hydrogen bonds generate (12) loops and the dimers are further linked by weak C-H⋯F inter-actions to form [01] chains.
摘要
在标题化合物CHFN中，五元稠环体系高度褶皱，中心吡啶环与悬垂二氟苯环之间的二面角为45.12 (12)°。在晶体中，通过成对的弱C-H⋯N氢键相连的反演二聚体形成(12)环，并且这些二聚体通过弱C-H⋯F相互作用进一步相连形成[01]链。
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