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-聚[[氯代-三-(1,3-噻唑烷-2-硫酮-κ)镉(II)]-μ-氯代]

-Poly[[chlorido-tris-(1,3-thia-zolidine-2-thione-κ)cadmium(II)]-μ-chlorido].

作者信息

Diop Aboubacar, Diop Tidiane, Kama Antoine Blaise, Diop Cheikh Abdou Khadre, Tumanov Nikolay

机构信息

Laboratoire de Chimie Minérale et Analytique (LA.CHI.MI.A), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

Departement de Chimie, Université de Namur, Rue de Bruxelles 61-5000, Namur, Belgium.

出版信息

IUCrdata. 2020 Oct 30;5(Pt 10):x201423. doi: 10.1107/S2414314620014236. eCollection 2020 Oct.

DOI:10.1107/S2414314620014236
PMID:36339031
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462165/
Abstract

The synthesis and characterization of poly[di-chlorido-tri(1,3-thia-zolidine-2-thione)cadmium(II)], [CdCl(CHNS)] , prepared from CdCl·HO and CHNS (tzdSH) in a 1:3 ratio, are described. The Cd cation is coordinated by three 1,3-thia-zolidine-2-thione mol-ecules and three Cl anions in a distorted octa-hedral environment. The Cd metal centres are connected Cl ligands, creating polymeric chains running along the axis direction. The conformation of the chains is stabilized by N-H⋯Cl hydrogen bonds.

摘要

描述了由氯化镉·水合物（CdCl₂·H₂O）和1,3 - 噻唑烷 - 2 - 硫酮（CHNS，tzdSH）以1:3的比例制备的聚[二氯 - 三（1,3 - 噻唑烷 - 2 - 硫酮）镉（II）]，[CdCl(CHNS)₃]的合成与表征。镉阳离子在扭曲的八面体环境中由三个1,3 - 噻唑烷 - 2 - 硫酮分子和三个氯阴离子配位。镉金属中心通过氯配体相连，形成沿轴方向延伸的聚合物链。链的构象通过N - H⋯Cl氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e089/9462165/dd6044cf1cbd/x-05-x201423-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e089/9462165/296b70869ea2/x-05-x201423-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e089/9462165/dd6044cf1cbd/x-05-x201423-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e089/9462165/296b70869ea2/x-05-x201423-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e089/9462165/dd6044cf1cbd/x-05-x201423-fig2.jpg

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本文引用的文献

1
Crystal structure of [3-(4,5-di-hydro-1,3-thia-zolin-2-yl-κN)-1,3-thia-zolidine-2-thione-κS (2)](1,3-thia-zol-idine-2-thione-κS (2))copper(I) nitrate.[3-(4,5-二氢-1,3-噻唑啉-2-基-κN)-1,3-噻唑烷-2-硫酮-κS(2)](1,3-噻唑烷-2-硫酮-κS(2))硝酸铜(I)的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Jul 19;70(Pt 8):91-3. doi: 10.1107/S160053681401544X. eCollection 2014 Aug 1.
2
Use of intensity quotients and differences in absolute structure refinement.强度商数的使用及绝对结构精修中的差异
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2013 Jun;69(Pt 3):249-59. doi: 10.1107/S2052519213010014. Epub 2013 May 17.
3
(Acetato-κO)(acetato-κO,O')bis-(1,3-diazinane-2-thione-κS)cadmium(II).
（乙酸根-κO）（乙酸根-κO,O'）双（1,3-二氮杂环己烷-2-硫酮-κS）镉（II）
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1352-3. doi: 10.1107/S1600536812041852. Epub 2012 Oct 13.