Suen Maw-Cherng, Yeh Chun-Wei, Jou Chi-Hsiung
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1082. doi: 10.1107/S1600536811027048. Epub 2011 Jul 13.
In the title coordination polymer, CdCl(2)(C(2)H(3)N(3)S), the Cd(II) cation is coordinated by four Cl(-) anions and two N atoms from two trans 2-amino-1,3,4-thia-diazole (L) ligands in a distorted octa-hedral geometry. The L ligand and Cl(-) anions bridge adjacent Cd cations, forming a polymeric chain along the b axis; the separation between adjacent Cd cations is 3.619 (1) Å. In the crystal, the polymeric chains are inter-linking through N-H⋯Cl hydrogen bonds between the L ligands and Cl(-) anions.
在标题配位聚合物[CdCl₂(C₂H₃N₃S)]ₙ中，Cd(II)阳离子由四个Cl⁻阴离子和来自两个反式2-氨基-1,3,4-噻二唑（L）配体的两个N原子以扭曲的八面体几何构型配位。L配体和Cl⁻阴离子桥连相邻的Cd阳离子，沿b轴形成一条聚合物链；相邻Cd阳离子之间的间距为3.619 (1) Å。在晶体中，聚合物链通过L配体与Cl⁻阴离子之间的N—H⋯Cl氢键相互连接。
