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4-溴-2-[({2-[(2-羟乙基)氨基]乙基}亚氨基)-甲基]苯酚

4-Bromo-2-[({2-[(2-hy-droxy-eth-yl)amino]-eth-yl}imino)-meth-yl]phenol.

作者信息

Samoľová Erika, Dehno Khalaji Aliakbar, Eigner Václav

机构信息

Institute of Physics AS CR, v.v.i., Na Slovance 2, 182 21 Prague 8, Czech Republic.

Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran.

出版信息

IUCrdata. 2021 Apr 9;6(Pt 4):x210335. doi: 10.1107/S2414314621003357. eCollection 2021 Apr.

DOI:10.1107/S2414314621003357
PMID:36339102
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462328/
Abstract

The new title Schiff base compound, CHBrNO, crystallizes in the monoclinic space group 2 with two independent mol-ecules in the asymmetric unit. It was prepared by the condensation reaction of 5-bromo-2-hy-droxy-benzaldehyde and amino-ethyl-ethano-lamine. There is an intra-molecular O-H⋯N hydrogen bond with an (6) ring motif. Moreover, there are inter-molecular C-H⋯N, C-H⋯O and Br⋯O inter-actions in the crystal structure of the title compound.

摘要

新型席夫碱化合物CHBrNO以单斜晶系空间群2结晶，不对称单元中有两个独立分子。它是由5-溴-2-羟基苯甲醛与氨基乙基乙醇胺通过缩合反应制备而成。存在一个具有(6)环模式的分子内O-H⋯N氢键。此外，在该标题化合物的晶体结构中存在分子间C-H⋯N、C-H⋯O和Br⋯O相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/718f/9462328/113d75a7133b/x-06-x210335-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/718f/9462328/b776ec495d8c/x-06-x210335-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/718f/9462328/113d75a7133b/x-06-x210335-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/718f/9462328/b776ec495d8c/x-06-x210335-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/718f/9462328/113d75a7133b/x-06-x210335-fig2.jpg

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