4-溴-2-[(E)-(2-{2-[(2-{[(E)-5-溴-2-羟基苄叉基]氨基}-苯基)硫烷基]乙硫烷基}苯基)亚氨基甲基]苯酚
4-Bromo-2-[(E)-(2-{2-[(2-{[(E)-5-bromo-2-hy-droxy-benzyl-idene]amino}-phen-yl)sulfan-yl]ethyl-sulfan-yl}phen-yl)imino-meth-yl]phenol.
作者信息
Kargar Hadi, Kia Reza, Tahir Muhammad Nawaz
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2635. doi: 10.1107/S1600536812034071. Epub 2012 Aug 4.
Abstract
The asymmetric unit of the title compound, C(28)H(22)Br(2)N(2)O(2)S(2), comprises half of a Schiff base ligand, the whole mol-ecule being generated by a crystallographic inversion center located at the mid-point of the C-C bond of the central methyl-ene segment. Intra-molecular O-H⋯N and O-H⋯S hydrogen bonds make S(6) and S(5) ring motifs, respectively. In the crystal, there are no significant inter-molecular inter-actions.
摘要
标题化合物C(28)H(22)Br(2)N(2)O(2)S(2)的不对称单元包含半个席夫碱配体，整个分子由位于中心亚甲基片段C-C键中点的晶体学倒转中心产生。分子内的O-H⋯N和O-H⋯S氢键分别形成S(6)和S(5)环模式。在晶体中，不存在显著的分子间相互作用。
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