（氯/溴）[（1,2,5,6-η）-环辛-1,5-二烯]（4-异丙基-1-甲基-1,2,4-三唑-5-亚基）铑（I）
(Chlorido/bromido)[(1,2,5,6-η)-cyclo-octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl-idene)rhodium(I).
作者信息
Rushlow Joshua, Astashkin Andrei V, Albert Daniel R, Rajaseelan Edward
机构信息
Department of Chemistry, Millersville University, Millersville, PA 17551, USA.
Department of Chemistry and Biochemistry, The University of Arizona, Tuscon, AZ, 85716, USA.
出版信息
IUCrdata. 2021 Aug 13;6(Pt 8):x210811. doi: 10.1107/S2414314621008117. eCollection 2021 Aug.
A new triazole-based neutral Rh complex, [Rh(ClBr)(CHN)(CH)], has been synthesized and structurally characterized. The Rh atom has a distorted square-planar coordination environment, formed by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.154). No significant inter-molecular inter-actions other than van der Waals forces are found in the crystal structure. Diffraction data indicated a two-component inversion twin with a ratio of 0.95 (5):0.05 (5).
一种基于三唑的新型中性铑配合物[Rh(ClBr)(CHN)(CH)]已被合成并进行了结构表征。铑原子具有扭曲的平面正方形配位环境，由双齿环辛-1,5-二烯（COD）配体、N-杂环卡宾和显示取代无序的卤化物配体（Cl:Br = 0.846:0.154）形成。在晶体结构中，除范德华力外未发现明显的分子间相互作用。衍射数据表明存在两组分倒易孪晶，比例为0.95 (5):0.05 (5)。
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