氯代 - [(1,2,5,6 - η)-环辛 - 1,5 - 二烯](1 - 乙基 - 4 - 异丁基 - 1,2,4 - 三唑 - 5 - 亚基)铑(I)
Chlorido-[(1,2,5,6-η)-cyclo-octa-1,5-diene](1-ethyl-4-isobutyl-1,2,4-triazol-5-yl-idene)rhodium(I).
作者信息
Lerch Timothy G, Gau Michael, Albert Daniel R, Rajaseelan Edward
机构信息
Department of Chemistry Millersville University,Millersville PA 17551 USA.
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104, USA.
出版信息
IUCrdata. 2024 Jul 23;9(Pt 7):x240704. doi: 10.1107/S2414314624007041. eCollection 2024 Jul.
A new neutral triazole-based N-heterocyclic carbene rhodium(I) complex [RhCl(CH)(CHN)], has been synthesized and structurally characterized. The complex crystallizes with two mol-ecules in the asymmetric unit. The central rhodium(I) atom has a distorted square-planar coordination environment, formed by a cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene (NHC) ligand, and a chlorido ligand. The bond lengths are unexceptional. A weak inter-molecular non-standard hydrogen-bonding inter-action exists between the chlorido and NHC ligands.
一种新型的基于中性三唑的N-杂环卡宾铑（I）配合物[RhCl(CH)(CHN)]已被合成并进行了结构表征。该配合物在不对称单元中含有两个分子结晶。中心铑（I）原子具有扭曲的平面正方形配位环境，由一个环辛-1,5-二烯（COD）配体、一个N-杂环卡宾（NHC）配体和一个氯配体形成。键长并无异常。氯配体和NHC配体之间存在弱的分子间非标准氢键相互作用。
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