六水十二-μ-氯代-六碘化二铌
Hexa-aquadodeca-μ-chlorido--hexa-niobium diiodide.
作者信息
Schröder Florian, Köckerling Martin
机构信息
Universität Rostock, Institut für Chemie, Anorganische Festkörperchemie, Albert-Einstein-Str. 3a, D-18059 Rostock, Germany.
出版信息
IUCrdata. 2021 Jul 20;6(Pt 7):x210696. doi: 10.1107/S2414314621006969. eCollection 2021 Jul.
Abstract
The title compound, [NbCl(HO)]I, consists of the niobium cluster cation [NbCl(HO)] and two non-coordinating, charge-balancing iodide ions. The edges of the Nb octa-hedron are bridged by chlorido ligands. Each Nb atom is further coordinated by a water ligand. The cluster cation has a charge of +2, which is balanced by that of two iodide anions.
摘要
标题化合物[NbCl(HO)]I由铌簇阳离子[NbCl(HO)]和两个非配位的电荷平衡碘离子组成。铌八面体的棱边由氯配体桥连。每个铌原子还与一个水配体配位。簇阳离子的电荷为 +2，由两个碘阴离子的电荷平衡。
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