• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

四羰基二-μ-氯代-二氯代-双-(η-环戊二烯基)二铁二镓(2)

Tetra-carbonyldi-μ-chlorido-di-chlorido-bis-(η-cyclo-penta-dien-yl)diirondigallium(2 ).

作者信息

Harakas George N, Demmin Mary Elizabeth

机构信息

PO Box 6949, Radford University, Radford, Virginia 24142, USA.

出版信息

IUCrdata. 2022 Aug 26;7(Pt 8):x220832. doi: 10.1107/S241431462200832X. eCollection 2022 Aug.

DOI:10.1107/S241431462200832X
PMID:36340981
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9635419/
Abstract

The title compound, [FeGa(CH)Cl(CO)], has an iron-gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol-ecule has an inversion center located between the gallium atoms. The cyclo-penta-dienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site.

摘要

标题化合物[FeGa(CH)Cl(CO)]的铁-镓键长为2.3028 (3) Å。镓原子通过两个桥连氯原子相连，每个镓原子还带有一个端基氯原子。分子在镓原子之间有一个对称中心。环戊二烯基配体在两个位置上无序分布，主要占据位置的占有率为0.57 (2)。

相似文献

1
Tetra-carbonyldi-μ-chlorido-di-chlorido-bis-(η-cyclo-penta-dien-yl)diirondigallium(2 ).四羰基二-μ-氯代-二氯代-双-(η-环戊二烯基)二铁二镓(2)
IUCrdata. 2022 Aug 26;7(Pt 8):x220832. doi: 10.1107/S241431462200832X. eCollection 2022 Aug.
2
Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido-borylene-1:2κ(2) B:B-[1(η(5))-penta-methyl-cyclo-penta-dien-yl](tri-cyclo-hexyl-phosphane-2κP)iron(II)platinum(II) benzene monosolvate.μ-1κC:2(η(2))-羰基-羰基-1κC-氯代-2κCl-μ-氯代-硼烯-1:2κ(2)B:B-[1(η(5))-五甲基-环戊二烯基](三环己基膦-2κP)铁(II)铂(II)苯单溶剂合物的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 29;70(Pt 11):421-3. doi: 10.1107/S1600536814023381. eCollection 2014 Nov 1.
3
Di-μ2-chlorido-bis-[chlorido(η(5)-2,3,4,5-tetra-methyl-1-propyl-cyclo-penta-dien-yl)iridium(III)].二-μ2-氯-双-[氯（η(5)-2,3,4,5-四甲基-1-丙基-环戊二烯基）铱（III）]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m176. doi: 10.1107/S1600536813005072. Epub 2013 Feb 28.
4
trans-Di-μ-carbonyl-bis-{carbon-yl[η-2,3,4,5-tetra-methyl-1-(5-methyl-2-fur-yl)cyclo-penta-dien-yl]ruthenium(I)}(Ru-Ru).反式-二-μ-羰基-双-{羰基[η-2,3,4,5-四甲基-1-(5-甲基-2-呋喃基)环戊二烯基]钌(I)}(Ru-Ru)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m895. doi: 10.1107/S1600536809026075.
5
Redetermination of (acetonitrile-κN)dicarbon-yl(η(5)-cyclo-penta-dien-yl)iron(II) tetra-fluoridoborate.四氟硼酸（乙腈-κN）二羰基（η(5)-环戊二烯基）铁（II）的重新测定
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m966. doi: 10.1107/S1600536812027857. Epub 2012 Jun 23.
6
μ-Oxido-bis-[bis-(penta-fluoro-phenolato)(η-penta-methyl-cyclo-penta-dien-yl)titanium(IV)].μ-氧代-双-[双-(五氟苯酚根)(η-五甲基环戊二烯基)钛(IV)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1147. doi: 10.1107/S1600536811029357. Epub 2011 Jul 30.
7
Crystal structure of μ-oxido-1,1'κ(2) O:O-bis{tetra-μ-oxido-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-tris[1,2,3(η(5))-penta-methyl-cyclo-penta-dien-yl]-trianglo-trititanium(IV)}.μ-氧化-1,1'κ(2) O:O-双{四-μ-氧化-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-三[1,2,3(η(5))-五甲基-环戊二烯基]-三角-三钛(IV)}的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Mar 21;71(Pt 4):m97. doi: 10.1107/S2056989015004041. eCollection 2015 Apr 1.
8
[1,2-Bis(diphenyl-phosphino)ethane]-chlorido(η-penta-methyl-cyclo-penta-dien-yl)iron(II) dichloro-methane solvate.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 10;66(Pt 8):m921. doi: 10.1107/S1600536810026784.
9
trans-Di-μ-carbonyl-bis-{carbon-yl[η-2,3,4,5-tetra-methyl-1-(2-thien-yl)cyclo-penta-dien-yl]ruthenium(I)}(Ru-Ru).反式-二-μ-羰基-双-{羰基[η-2,3,4,5-四甲基-1-(2-噻吩基)环戊二烯基]钌(I)}(Ru-Ru)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m894. doi: 10.1107/S1600536809026063.
10
Crystal structure of bis-{μ2-[(2-imino-cyclo-pentyl-idene)methyl-idene]aza-nido-κ(2) N:N'}bis-[(η(5)-penta-methyl-cyclo-penta-dien-yl)zirconium(IV)] hexane monosolvate.双-{μ2-[(2-亚氨基-环戊叉基)亚甲基]氮杂巢式-κ(2) N:N'}双-[(η(5)-五甲基环戊二烯基)锆(IV)]己烷单溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 14;71(Pt 12):m219-20. doi: 10.1107/S2056989015021234. eCollection 2015 Dec 1.

本文引用的文献

1
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination.用于单晶结构测定的银和钼微焦点X射线源的比较。
J Appl Crystallogr. 2015 Jan 30;48(Pt 1):3-10. doi: 10.1107/S1600576714022985. eCollection 2015 Feb 1.
2
ShelXle: a Qt graphical user interface for SHELXL.ShelXle：用于SHELXL的Qt图形用户界面。
J Appl Crystallogr. 2011 Dec 1;44(Pt 6):1281-1284. doi: 10.1107/S0021889811043202. Epub 2011 Nov 12.
3
Terminal Coordination of a Gallium(I) Species to a Transition Metal. Syntheses and Crystal Structures of Ru{GaCl(THF)(2)}{GaCl(2)(THF)}(2)(CO)(3).0.5THF and Ru(2){GaCl(2)(THF)}(2)(CO)(8).
镓（I）物种与过渡金属的末端配位。Ru{GaCl(THF)(2)}{GaCl(2)(THF)}(2)(CO)(3).0.5THF和Ru(2){GaCl(2)(THF)}(2)(CO)(8)的合成与晶体结构
Inorg Chem. 1997 Jun 18;36(13):2704-2707. doi: 10.1021/ic9613772.