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反式-二-μ-羰基-双-{羰基[η-2,3,4,5-四甲基-1-(2-噻吩基)环戊二烯基]钌(I)}(Ru-Ru)

trans-Di-μ-carbonyl-bis-{carbon-yl[η-2,3,4,5-tetra-methyl-1-(2-thien-yl)cyclo-penta-dien-yl]ruthenium(I)}(Ru-Ru).

作者信息

Ma Zhi-Hong, Dong Gui-Ying, Liu Xiao-Huan, Lin Jin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m894. doi: 10.1107/S1600536809026063.

DOI:10.1107/S1600536809026063
PMID:21583356
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977155/
Abstract

The title compound, [Ru(2)(C(13)H(15)S)(2)(CO)(4)], is a centrosymmetric binuclear metal-carbonyl complex containing an Ru-Ru single bond [2.7511 (8) Å]. Each Ru(I) atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η(5)-cyclo-penta-dienyl group. The complex has a trans conformation and the two cyclo-penta-dienyl ring planes are parallel. The crystal structure involves weak C-H⋯O hydrogen bonds.

摘要

标题化合物[Ru₂(C₁₃H₁₅S)₂(CO)₄]是一种含有Ru-Ru单键[2.7511 (8) Å]的中心对称双核金属羰基配合物。每个Ru(I)原子由两个桥连羰基配体、一个端基羰基配体和一个η⁵-环戊二烯基配位。该配合物具有反式构象，且两个环戊二烯基环平面相互平行。晶体结构存在弱的C-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9633/2977155/bcd94236a56b/e-65-0m894-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9633/2977155/bcd94236a56b/e-65-0m894-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9633/2977155/bcd94236a56b/e-65-0m894-fig1.jpg

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