Su Caihong, Li Yancai, Zhu Jiabin, Gao Yuan, Li Qi, Du Shuangkui, Yu Xiuzhu
Shaanxi Union Research Center of University and Enterprise for Functional Oil Engineering Technology, College of Food Science and Engineering, Northwest A&F University 22 Xinong Road Yangling 712100 Shaanxi P. R. China
RSC Adv. 2022 Oct 27;12(47):30734-30741. doi: 10.1039/d2ra04341f. eCollection 2022 Oct 24.
The present study aimed to decrease the brittleness of flaxseed oleogels based on candelilla wax (CLW) in combination with flaxseed gum (FG). Effects of flaxseed gum concentrations (0-0.4%) on the characteristics of flaxseed oleogels including oil binding capacity, textural, thermal, and rheological properties, and crystal polymorphisms were investigated. Higher concentrations (≥0.2%) of FG significantly decreased the textural parameters (, hardness, fracturability) of oleogels ( < 0.05), suggesting that FG could decrease brittleness. Rheological results indicated that all flaxseed oleogels exhibited solid-like characteristics because the elastic modulus was larger than the viscous modulus. The elastic modulus of flaxseed oleogels presented a maximum value at 0.1% gum concentration. Any increase in gum concentration beyond this concentration decreased the elastic modulus. Increasing FG concentration up to 0.4% decreased the enthalpy of flaxseed oleogels during the melting process. The β'-polymorphic form is an orthorhombic perpendicular (O) subcell structure. Similar β' crystal forms were observed among flaxseed oleogels, indicating that FG did not affect them negatively. The study showed that the physical properties of flaxseed oleogels based on CLW could be significantly changed by FG addition. These results provided a deeper comprehension of the novel system, which should be considered a new way to obtain healthy fats with better plasticity for food applications.
本研究旨在降低基于小烛树蜡(CLW)与亚麻籽胶(FG)组合的亚麻籽油凝胶的脆性。研究了亚麻籽胶浓度(0 - 0.4%)对亚麻籽油凝胶特性的影响,包括油结合能力、质地、热性能、流变性能和晶体多晶型。较高浓度(≥0.2%)的FG显著降低了油凝胶的质地参数(如硬度、易碎性)(P < 0.05),表明FG可降低脆性。流变学结果表明,所有亚麻籽油凝胶均表现出类固体特性,因为弹性模量大于粘性模量。亚麻籽油凝胶的弹性模量在胶浓度为0.1%时呈现最大值。超过此浓度后,胶浓度的任何增加都会降低弹性模量。将FG浓度增加至0.4%可降低亚麻籽油凝胶在熔化过程中的焓。β'-多晶型是一种正交垂直(O)亚晶胞结构。在亚麻籽油凝胶中观察到类似的β'晶体形式,表明FG对其没有负面影响。研究表明,添加FG可显著改变基于CLW的亚麻籽油凝胶的物理性质。这些结果为该新型体系提供了更深入的理解,应将其视为一种获得具有更好可塑性的健康脂肪以用于食品应用的新方法。