Zeng Jing, Wang Weifei, Chen Ying, Liu Xuan, Xu Qingqing, Qi Suijian, Lan Dongming, Wang Yonghua
Department of Food Science and Engineering, School of Food Science and Engineering, South China University of Technology, Guangzhou 510640, China.
Sericultural and Agri-Food Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510610, China.
Foods. 2022 Nov 3;11(21):3489. doi: 10.3390/foods11213489.
The processing technique is one of the key factors affecting the quality of camellia oil. In this study, camellia oils were obtained using four different processing techniques (cold-pressed, roast-pressed, fresh-pressed, and refined), and their triacylglycerols (TAGs) profile, bioactive compound (tocopherols, sterols, squalene, and polyphenols) level, oxidative stability, and volatile compounds were analyzed and compared. To further identify characteristic components in four camellia oil products, the TAG profile was analyzed using UPLC-QTOF-MS. Five characteristic markers were identified, including OOO ( 902.8151), POL ( 874.7850), SOO ( 904.8296), PPL ( 848.7693), PPS ( 852.7987). Regarding the bioactive compound level and antioxidant capacity, the fresh-pressed technique provided higher α-tocopherols (143.15 mg/kg), β-sitosterol (93.20 mg/kg), squalene (102.08 mg/kg), and polyphenols (35.38 mg/kg) and showed stronger overall oxidation stability and antioxidant capacity. Moreover, a total of 65 volatile compounds were detected and identified in four camellia oil products, namely esters (23), aldehydes (19), acids (8), hydrocarbons (3), ketones (3), and others (9), among which pressed oil was dominated by aldehydes, acid, and esters, while refined oil had few aroma components. This study provided a comprehensive comparative perspective for revealing the significant influence of the processing technique on the camellia oil quality and its significance for producing camellia oil of high quality and with high nutritional value.
加工工艺是影响山茶油品质的关键因素之一。在本研究中,采用四种不同的加工工艺(冷榨、热榨、鲜榨和精炼)制取山茶油,并对其甘油三酯(TAGs)谱、生物活性成分(生育酚、甾醇、角鲨烯和多酚)含量、氧化稳定性和挥发性化合物进行了分析和比较。为进一步鉴定四种山茶油产品中的特征成分,采用超高效液相色谱-四极杆飞行时间质谱联用仪(UPLC-QTOF-MS)分析了TAG谱。鉴定出五个特征标志物,包括OOO(902.8151)、POL(874.7850)、SOO(904.8296)、PPL(848.7693)、PPS(852.7987)。在生物活性成分含量和抗氧化能力方面,鲜榨工艺得到的α-生育酚(143.15毫克/千克)含量更高,β-谷甾醇(93.20毫克/千克)、角鲨烯(102.08毫克/千克)和多酚(35.38毫克/千克)含量更高,总体氧化稳定性和抗氧化能力更强。此外,在四种山茶油产品中共检测并鉴定出65种挥发性化合物,即酯类(23种)、醛类(19种)、酸类(8种)、烃类(3种)、酮类(3种)和其他(9种),其中压榨油以醛类、酸类和酯类为主,而精炼油的香气成分较少。本研究为揭示加工工艺对山茶油品质的显著影响及其对生产高品质、高营养价值山茶油的意义提供了全面的比较视角。