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石墨烯类型和含量对碳化硅/石墨烯纳米复合材料在水环境中摩擦磨损的影响

Influence of Graphene Type and Content on Friction and Wear of Silicon Carbide/Graphene Nanocomposites in Aqueous Environment.

作者信息

Schlüter Bernadette, Schröder Christian, Zhang Wenli, Mülhaupt Rolf, Degenhardt Ulrich, Sedlák Richard, Dusza Ján, Balázsi Katalin, Balázsi Csaba, Kailer Andreas

机构信息

Fraunhofer Institute for Mechanics of Materials IWM, Woehlerstr. 11, 79108 Freiburg, Germany.

Freiburg Materials Research Center (FMF), Institute for Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. 21, 79104 Freiburg, Germany.

出版信息

Materials (Basel). 2022 Nov 3;15(21):7755. doi: 10.3390/ma15217755.

Abstract

Two different types of graphene materials were used as functional nanofillers for the mechanical and tribological improvement of silicon carbide/graphene nanocomposites. On the one hand is thermally reduced graphite oxide (TRGO) reduced at three different temperatures, and on the other hand is graphene made of three different organic precursors, which were directly coated on silicon carbide (SiC) platelets (GSiC). Additionally, benchmark materials were also used as carbon fillers. The SiC/graphene nanocomposites with 2 wt% filler content were manufactured by pressureless sintering (PLS). Some composites were produced with higher graphene contents of 4% and 8% and sintered by spark plasma sintering (SPS). Microstructural analyses were conducted using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Underwater lubrication, the SP sintered TRGO and GSiC materials with high graphene content have shown the most promising tribological performance. Furthermore, the reduced size of the homogeneously distributed nanoparticles promotes the formation of surface states, which improve the friction and wear properties.

摘要

两种不同类型的石墨烯材料被用作功能纳米填料,以改善碳化硅/石墨烯纳米复合材料的机械性能和摩擦学性能。一方面是在三种不同温度下还原的热还原氧化石墨烯(TRGO),另一方面是由三种不同有机前驱体制备的石墨烯,它们被直接涂覆在碳化硅(SiC)片上(GSiC)。此外,基准材料也用作碳填料。填料含量为2 wt%的SiC/石墨烯纳米复合材料通过无压烧结(PLS)制备。一些复合材料的石墨烯含量更高,为4%和8%,并通过放电等离子烧结(SPS)进行烧结。使用扫描电子显微镜(SEM)和透射电子显微镜(TEM)进行微观结构分析。在水下润滑条件下,具有高石墨烯含量的SPS烧结TRGO和GSiC材料表现出最有前景的摩擦学性能。此外,均匀分布的纳米颗粒尺寸减小促进了表面态的形成,从而改善了摩擦和磨损性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2827/9655182/a394e87ea1cb/materials-15-07755-g001.jpg

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