Turkoglu Sevil, Zhang Jinde, Dodiuk Hanna, Kenig Samuel, Ratto Jo Ann, Mead Joey
Plastics Engineering Department, University of Massachusetts Lowell, Lowell, MA 01854, USA.
Department of Polymer Materials Engineering, Shenkar College, Ramat Gan 5252626, Israel.
Polymers (Basel). 2022 Nov 1;14(21):4663. doi: 10.3390/polym14214663.
The effect of particle loading on the wetting properties of coatings was investigated by modifying a coating formulation based on hydrophilic silica nanoparticles and poly (acrylic acid) (PAA). Water contact angle (WCA) measurements were conducted for all coatings to characterize the surface wetting properties. Wettability was improved with an increase in particle loading. The resulting coatings showed superhydrophilic (SH) behavior when the particle loading was above 53 vol. %. No new peaks were detected by attenuated total reflection (ATR-FTIR). The surface topography of the coatings was studied by atomic force microscopy (AFM) and scanning electron microscopy (SEM). The presence of hydrophilic functional groups and nano-scale roughness were found to be responsible for superhydrophilic behavior. The surface chemistry was found to be a primary factor determining the wetting properties of the coatings. Adhesion of the coatings to the substrate was tested by tape test and found to be durable. The antifogging properties of the coatings were evaluated by exposing the films under different environmental conditions. The SH coatings showed anti-fogging behavior. The transparency of the coatings was significantly improved with the increase in particle loading. The coatings showed good transparency (>85% transmission) when the particle loading was above 84 vol. %.
通过对基于亲水性二氧化硅纳米颗粒和聚(丙烯酸)(PAA)的涂料配方进行改性,研究了颗粒负载对涂料润湿性的影响。对所有涂料进行水接触角(WCA)测量,以表征表面润湿性。随着颗粒负载的增加,润湿性得到改善。当颗粒负载高于53体积%时,所得涂料表现出超亲水(SH)行为。衰减全反射(ATR-FTIR)未检测到新的峰。通过原子力显微镜(AFM)和扫描电子显微镜(SEM)研究了涂料的表面形貌。发现亲水性官能团的存在和纳米级粗糙度是超亲水行为的原因。发现表面化学是决定涂料润湿性的主要因素。通过胶带试验测试了涂料与基材的附着力,发现其具有耐久性。通过在不同环境条件下暴露薄膜来评估涂料的防雾性能。超亲水涂料表现出防雾行为。随着颗粒负载的增加,涂料的透明度显著提高。当颗粒负载高于84体积%时,涂料表现出良好的透明度(透过率>85%)。