Improved Performance of Polylactic Acid Biocomposites at High Lignin Loadings through Glycidyl Methacrylate Grafting of Melt-Flowable Organosolv Lignin.

Glycidyl methacrylate (GMA) was grafted onto a melt-flowable organosolv lignin, called bioleum (BL), using a melt mixing process. Then, up to 40 wt % of BL--GMA was blended with polylactic acid (PLA) in the presence of dicumyl peroxide as a free radical initiator utilizing a melt extrusion method. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis, differential scanning calorimetry, scanning electron microscopy, and tensile testing were performed to characterize the biocomposites' performance. The FTIR results revealed a successful grafting of GMA onto BL. Overall, BL and PLA compatibility increased significantly with the grafting and resulted in decreased domain size of BL--GMA and thus enhanced all the tensile properties (strength, modulus, and elongation at break) at BL loadings as high as 40 wt %. For instance, in the biocomposites containing 30 wt % BL, the GMA grafting increased the tensile strength by 23%. The presence of BL and BL--GMA hindered PLA's crystallization even when it was cooled at a rate of 1 °C/min. However, the composites with BL--GMA showed a crystallinity value comparable to that of PLA during isothermal crystallization, but with a slower crystallization rate. This work reveals a facile and scalable method that can be adopted to enhance the performance of lignin-based biocomposites.