He Chang, Yang Zhe, Ning Yu, Yang Sen, Jiang Fengcheng, Zhang Jiayi
School of Environmental Studies, China University of Geosciences, Wuhan, 430078, China.
Institute of Resources and Environment, Henan Polytechnic University, Jiaozuo, 454003, China.
Environ Sci Pollut Res Int. 2023 Mar;30(11):28975-28989. doi: 10.1007/s11356-022-24309-6. Epub 2022 Nov 19.
Recently, there has been a clear understanding of the mechanism and influencing factors of ferrihydrite (Fh) phase transformation catalyzed by Fe(II); however, these factors mainly belong to environmental conditions and exogenous substances. And there is a lack of research on the effect of soil composition and structure on the phase transformation of Fh. Therefore, this study investigated the effects of montmorillonite (Mt) on the adsorption of Fe(II) and phase transformation of Fh under near-neutral pH. The initial rates ([Formula: see text]) of Elovich equation demonstrated the addition of Mt inhibited the adsorption of Fh but simultaneously accelerated the initial adsorption, thus increasing the adsorption of the system (e.g., 22.09-25.03 mg/g as increased Mt under pH 6.5) due to its high surface charge density. Increased pH enhances the surface charge density by promoting the deprotonation of the surface group (Fe-OH, Al-OH, and Si-OH) and consequently increases adsorption of Fe(II) (e.g., 17.97-22.09 mg/g as increased pH of pure Fh). Based on the previous method of extracting labile Fe(III), we found that pH promotes the initial formation of labile Fe(III) by increasing electron transfer and promoting recrystallization caused by bridging condensation, via increased -OH. Although Mt inhibits the adsorption of Fh, it promotes the formation of labile Fe(III) by increasing the system adsorption and bond with Fh. The results of the analysis of variance showed both pH and solid ratio influence significantly on the maximum adsorption (p = 6.81 × 10 and 2.54 × 10) and the conversion ratios of labile Fe(III) (p = 3.43 × 10 and 9.16 × 10).
