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用纳米材料功能化的聚合物膜(MP@NMs):农药去除进展综述

Polymeric membranes functionalized with nanomaterials (MP@NMs): A review of advances in pesticide removal.

作者信息

Sanoja-López Kelvin Adrian, Quiroz-Suárez Kevin Alberto, Dueñas-Rivadeneira Alex Alberto, Maddela Naga Raju, Montenegro Maria C B S M, Luque Rafael, Rodríguez-Díaz Joan Manuel

机构信息

Departamento de Procesos Químicos, Facultad de Ciencias Matemáticas, Físicas y Químicas, Universidad Técnica de Manabí, Portoviejo, Manabí, 130104, Ecuador; Laboratorio de Análisis Químicos y Biotecnológicos, Instituto de Investigación, Universidad Técnica de Manabí, Portoviejo, Manabí, 130104, Ecuador.

Departamento de Procesos Agroindustriales, Facultad de Ciencias Zootécnicas, Universidad Técnica de Manabí, Portoviejo, Manabí, 130104, Ecuador.

出版信息

Environ Res. 2023 Jan 15;217:114776. doi: 10.1016/j.envres.2022.114776. Epub 2022 Nov 17.

Abstract

The excessive contamination of drinking water sources by pesticides has a pernicious impact on human health and the environment since only 0.1% of pesticides is utilized effectively to control the and the rest is deposited in the environment. Filtration by polymeric membranes has become a promising technique to deal with this problem; however, the scientific community, in the need to find better pesticide retention results, has begun to meddle in the functionalization of polymeric membranes. Given the great variety of membrane, polymer, and nanomaterial synthesis methods present in the market, the possibilities of obtaining membranes that adjust to different variables and characteristics related to a certain pesticide are relatively extensive, so it is expected that this technology will represent one of the main pesticide removal strategies in the future. In this direction, this review focused on, - the main characteristics of the nanomaterials and their impact on pristine polymeric membranes; - the removal performance of functionalized membranes; and - the main mechanisms by which membranes can retain pesticides. Based on these insights, the functionalized polymeric membranes can be considered as a promising technology in the removal of pesticides since the removal performance of this technology against pesticide showed a significant increase. Obtaining membranes that adjust to different variables and characteristics related to a certain pesticide are relatively extensive, so it is expected that functionalized membrane technology will represent one of the main pesticide removal strategies in the future.

摘要

农药对饮用水源的过度污染会对人类健康和环境产生有害影响,因为只有0.1%的农药能有效用于防治病虫害,其余的则沉积在环境中。聚合物膜过滤已成为解决这一问题的一项很有前景的技术;然而,科学界为了获得更好的农药截留效果,已开始涉足聚合物膜的功能化研究。鉴于市场上存在各种各样的膜、聚合物和纳米材料合成方法,获得能够适应与特定农药相关的不同变量和特性的膜的可能性相对较大,因此预计这项技术将成为未来主要的农药去除策略之一。在此方向上,本综述聚焦于:- 纳米材料的主要特性及其对原始聚合物膜的影响;- 功能化膜的去除性能;- 膜截留农药的主要机制。基于这些见解,功能化聚合物膜可被视为一种很有前景的农药去除技术,因为该技术对农药的去除性能有显著提高。获得能够适应与特定农药相关的不同变量和特性的膜的可能性相对较大,因此预计功能化膜技术将成为未来主要的农药去除策略之一。

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