Aghayari Sedigheh
Sharif University of Technology, Tehran, Iran.
Heliyon. 2022 Nov 15;8(11):e11620. doi: 10.1016/j.heliyon.2022.e11620. eCollection 2022 Nov.
Polyvinylidene fluoride (PVDF) has special piezo/pyro/ferroelectric, flexibility, low weight, biocompatibility, economical, good chemical/thermal, and high mechanical properties, such as excellent nontoxic fiber/film formation. It has polar and nonpolar phases of α, β, γ, ε, and δ, in which the nonpolar α phase is the most stable one. However, the β phase is the best because it has good piezo/pyro/ferroelectric properties. Copolymers are attractive due to their low weight, nontoxic, chemical acid resistance, flexibility, and ease of processing. These aspects result in their applications in many fields. They are used for piezoelectric nanogenerators, cooling/heating sensors, electronic devices (fuel cells, lithium-ion batteries (as separators), dye-sensitive solar cells), filtration, oil/water separation, and photoelectric nanodevices. This review highlights the main aspects of the last decade's studies and focuses on the synthesis methods of PVDF nanofibers and their properties, leading to their applications in different sectors of industry.
聚偏氟乙烯(PVDF)具有特殊的压电/热释电/铁电性能、柔韧性、低重量、生物相容性、经济性、良好的化学/热稳定性以及高机械性能,例如能形成优异的无毒纤维/薄膜。它具有α、β、γ、ε和δ等极性和非极性相,其中非极性α相是最稳定的。然而,β相是最好的,因为它具有良好的压电/热释电/铁电性能。共聚物因其低重量、无毒、耐化学酸、柔韧性和易于加工而具有吸引力。这些特性使其在许多领域得到应用。它们用于压电纳米发电机、冷却/加热传感器、电子设备(燃料电池、锂离子电池(作为隔膜)、染料敏化太阳能电池)、过滤、油/水分离和光电纳米器件。本综述重点介绍了过去十年研究的主要方面,并聚焦于PVDF纳米纤维的合成方法及其性能,以及它们在不同工业领域的应用。