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基于聚偏氟乙烯的电纺压电纳米纤维：材料、结构及应用

Electrospun PVDF-based piezoelectric nanofibers: materials, structures, and applications.

作者信息

Zhang Mengdi, Liu Chengkun, Li Boyu, Shen Yutong, Wang Hao, Ji Keyu, Mao Xue, Wei Liang, Sun Runjun, Zhou Fenglei

机构信息

School of Textile Science and Engineering, Xi'an Polytechnic University Xi'an 710048 China

Key Laboratory of Functional Textile Material and Product of the Ministry of Education, Xi'an Polytechnic University Xi'an 710048 China.

出版信息

Nanoscale Adv. 2023 Jan 19;5(4):1043-1059. doi: 10.1039/d2na00773h. eCollection 2023 Feb 14.

DOI:10.1039/d2na00773h
PMID:36798499
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9926905/
Abstract

Polyvinylidene fluoride (PVDF) has been considered as a promising piezoelectric material for advanced sensing and energy storage systems because of its high dielectric constant and good electroactive response. Electrospinning is a straightforward, low cost, and scalable technology that can be used to create PVDF-based nanofibers with outstanding piezoelectric characteristics. Herein, we summarize the state-of-the-art progress on the use of filler doping and structural design to enhance the output performance of electrospun PVDF-based piezoelectric fiber films. We divide the fillers into single filler and double fillers and make comments on the effects of various dopant materials on the performance and the underlying mechanism of the PVDF-based piezoelectric fiber film. The effects of highly oriented structures, core-shell structures, and multilayer composite structures on the output properties of PVDF-based piezoelectric nanofibers are discussed in detail. Furthermore, the perspectives and opportunities for PVDF piezoelectric nanofibers in the fields of health care, environmental monitoring, and energy collection are also discussed.

摘要

聚偏氟乙烯（PVDF）因其高介电常数和良好的电活性响应，被认为是用于先进传感和能量存储系统的一种很有前景的压电材料。静电纺丝是一种简单、低成本且可扩展的技术，可用于制造具有出色压电特性的基于PVDF的纳米纤维。在此，我们总结了在使用填料掺杂和结构设计以提高静电纺丝PVDF基压电纤维膜输出性能方面的最新进展。我们将填料分为单一填料和双填料，并对各种掺杂材料对PVDF基压电纤维膜性能的影响及其潜在机制进行评论。详细讨论了高度取向结构、核壳结构和多层复合结构对PVDF基压电纳米纤维输出性能的影响。此外，还讨论了PVDF压电纳米纤维在医疗保健、环境监测和能量收集领域的前景和机遇。

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