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溴甲烷和乙二腈透过辐射松原木树皮的渗透特性比较

Comparison between the penetration characteristics of methyl bromide and ethanedinitrile through the bark of pine (Pinus radiata D.Don) logs.

作者信息

Hall Matthew K D, Adlam Anthony R

机构信息

The New Zealand Institute for Plant and Food Research Limited, Palmerston North, New Zealand.

Draslovka Services, North Melbourne, VIC, Australia.

出版信息

Pest Manag Sci. 2023 Apr;79(4):1442-1451. doi: 10.1002/ps.7316. Epub 2023 Jan 17.

DOI:10.1002/ps.7316
PMID:36495484
Abstract

BACKGROUND

Ethanedinitrile (EDN) is a fumigant being commercialized worldwide as an alternative phytosanitary treatment to methyl bromide (MB) for forest products. The penetration characteristics of MB and EDN were measured through the bark of wooden blocks (100 × 100 × 50 mm) cut from the upper (average bark thickness 5 ± 2 mm) and lower (average bark thickness 25 ± 5 mm) trunk of recently felled pine (Pinus radiata D.Don) trees. Doses of 48 g m  MB and 50 g m EDN were applied to chambers at 10 and 20°C for 10 h.

RESULTS

Penetration of MB was influenced by the interaction between fumigation time and temperature, with concentrations increasing at a higher rate at 20°C compared with at 10°C. After 10 h, an average concentration of 8.05 ± 0.89 g m had penetrated the bark of log sections at 20°C, whereas 5.20 ± 0.89 g m was measured at 10°C. By contrast, the factors examined in this study did not significantly impact the penetration of EDN. Concentration × time (CT) values for MB under the bark were 35.20 ± 2.30 g h m at 10°C and 55.85 ± 9.58 g h m at 20°C; whereas for EDN, CT values were 19.50 ± 6.80 g h m at 10°C and 19.08 ± 4.10 g h m at 20°C.

CONCLUSION

MB can achieve a higher concentration under the bark of log sections during simulated fumigations, but all of the factors examined affected the ability of MB to penetrate the bark of wooden blocks. By comparison, the penetration of EDN through the bark is more consistent than MB under laboratory conditions. © 2022 The Authors. Pest Management Science published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

摘要

背景

乙二腈(EDN)是一种在全球范围内商业化的熏蒸剂,作为甲基溴(MB)的替代植物检疫处理剂用于林产品。通过从最近砍伐的辐射松(Pinus radiata D.Don)树木的上部(平均树皮厚度5±2毫米)和下部(平均树皮厚度25±5毫米)树干切割的木块(100×100×50毫米)的树皮来测量MB和EDN的渗透特性。将48克/立方米的MB和50克/立方米的EDN剂量在10℃和20℃下施用于试验箱中10小时。

结果

MB的渗透受熏蒸时间和温度之间相互作用的影响,与10℃相比,在20℃时浓度增加速率更高。10小时后,在20℃时,平均浓度为8.05±0.89克/立方米的MB穿透了原木段的树皮,而在10℃时测量值为5.20±0.89克/立方米。相比之下,本研究中考察的因素对EDN的渗透没有显著影响。在10℃时,树皮下方MB的浓度×时间(CT)值为35.20±2.30克·小时/立方米,在20℃时为55.85±9.58克·小时/立方米;而对于EDN,在10℃时CT值为19.50±6.80克·小时/立方米,在20℃时为19.08±4.10克·小时/立方米。

结论

在模拟熏蒸过程中,MB可在原木段树皮下方达到更高浓度,但所有考察因素均影响MB穿透木块树皮的能力。相比之下,在实验室条件下,EDN通过树皮的渗透比MB更稳定。© 2022作者。由John Wiley & Sons Ltd代表化学工业协会出版的《害虫管理科学》。

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