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微腔萃取与分析热解联用技术探究不同条件下热压木材材料中挥发性有机化合物。

Microchamber Extraction and Analytical Pyrolysis to Explore Volatile Organic Compounds from Compression-Cooking Wood Materials Obtained under Different Conditions.

机构信息

Laboratoire de Chimie Agro-Industrielle, LCA, Université de Toulouse, INRAe, 4 allée Emile Monso, 31030 Toulouse, France.

Centre d'Application et de Traitement des Agro-Ressources (CATAR), Toulouse-INP, 4 allée Emile Monso, 31030 Toulouse, France.

出版信息

Molecules. 2022 Nov 26;27(23):8260. doi: 10.3390/molecules27238260.

Abstract

Volatile organic compounds are species of concern for indoor air quality. They are emitted from a wide range of indoor sources and in particular from construction materials. Industrialized wood-based panels made from various types of wood bonded with thermosetting adhesive resins have been shown to emit volatile organic compounds over months or even years mostly due to the petrochemical binders. Some studies have been conducted on binderless panels, but they mainly focused on the pressing parameters to be applied to optimize the panel characteristics. The aim of this research is to document the emissions from binderless panels and to access the volatile composition of wood processing through the molding of materials. For this purpose, binderless boards were manufactured from hardwoods, known to emit less than softwoods with different thermopressing temperatures and times. Emissions were studied by placing the materials in microchambers. Volatile organic compounds were then sampled and analyzed by various chromatographic methods. On the other hand, materials were pyrolyzed and then analyzed by gas chromatography and mass spectrometry. The implemented protocols proved suitable for the determination of more than 40 organic compounds, among which are aldehydes, aromatics, furans and derivatives, and carboxylic acids.

摘要

挥发性有机化合物是室内空气质量关注的物种。它们从各种室内源排放,特别是从建筑材料中排放。已经证明,由各种类型的木材制成的、用热固性粘合剂树脂粘合的工业化木质刨花板在数月甚至数年内会释放挥发性有机化合物,主要是由于石化粘合剂。已经对无粘合剂刨花板进行了一些研究,但它们主要侧重于应用于优化板特性的压制参数。本研究的目的是记录无粘合剂板的排放情况,并通过材料成型来了解木材加工的挥发性成分。为此,用不同的热压温度和时间制造了来自硬木的无粘合剂板,已知硬木的排放量低于软木。通过将材料放置在微室中来研究排放。然后通过各种色谱方法对挥发性有机化合物进行采样和分析。另一方面,将材料进行热解,然后通过气相色谱和质谱法进行分析。所实施的方案适合于测定 40 多种有机化合物,其中包括醛类、芳烃、呋喃及其衍生物和羧酸。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ad31/9735594/3a3aa9503421/molecules-27-08260-g001.jpg

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