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六种层状配位聚合物的超声辅助液相剥离的比较研究

Comparative study of sonication-assisted liquid phase exfoliation of six layered coordination polymers.

作者信息

Gosch Jonas, Synnatschke Kevin, Stock Norbert, Backes Claudia

机构信息

Christian-Albrechts-Universität zu Kiel, Max-Eyth-Straße 2, Kiel 24118, Germany.

University of Dublin, Trinity College, Dublin 2, SNIAM Building, Ireland.

出版信息

Chem Commun (Camb). 2022 Dec 22;59(1):55-58. doi: 10.1039/d2cc03366f.

Abstract

Sonication-assisted liquid phase exfoliation was applied to six different layered coordination polymers (CPs) in aqueous surfactant solution. The resulting nanosheets were investigated for structural and compositional integrity and microscopic analysis gives insights into the relationship between the crystal structure of the materials and their exfoliability. Larger open pores seem to favour the production of nanosheets with higher aspect ratio of lateral size to thickness.

摘要

在水性表面活性剂溶液中,采用超声辅助液相剥离法处理了六种不同的层状配位聚合物(CPs)。对所得纳米片的结构和成分完整性进行了研究,微观分析揭示了材料晶体结构与其可剥离性之间的关系。较大的开孔似乎有利于制备横向尺寸与厚度之比更高的纳米片。

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