芳基硼酸与三苯甲基异氰化物的氧化自由基转亚胺反应。
Oxidative Radical Transnitrilation of Arylboronic Acids with Trityl Isocyanide.
机构信息
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China.
出版信息
Org Lett. 2022 Dec 30;24(51):9403-9407. doi: 10.1021/acs.orglett.2c03778. Epub 2022 Dec 15.
PMID:36519782
Abstract
We report a radical transnitrilation of arylboronic acids with trityl isocyanide in the presence of manganese(III) acetate. Many functional groups can be tolerated in this transformation, and a special positive effect of benzoic acid in this reaction has been observed.
摘要
我们报道了在三苯甲基异氰酸酯和醋酸锰存在下芳基硼酸的彻底转亚氨基反应。在这种转化中可以容忍许多官能团，并且观察到苯甲酸在该反应中有特殊的积极影响。
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