钯催化芳基硼酸与异腈氧化偶联形成芳香羧酸。
Palladium-catalyzed oxidative coupling of arylboronic acid with isocyanide to form aromatic carboxylic acids.
作者信息
Chen Zhen-Bang, Liu Kui, Zhang Fang-Ling, Yuan Qing, Zhu Yong-Ming
机构信息
College of Pharmaceutical Sciences, Soochow University, Suzhou, 215123, China.
出版信息
Org Biomol Chem. 2017 Oct 4;15(38):8078-8083. doi: 10.1039/c7ob01428g.
PMID:28905063
Abstract
A valuable palladium-catalyzed oxidative coupling of aryl- and alkenyl borides with isocyanide for the synthesis of corresponding carboxylic acids has been developed. With wide substrate scopes and good functional group tolerance, this reaction offers corresponding carboxylic acids in moderate to excellent yields.
摘要
已开发出一种通过钯催化芳基硼化物和烯基硼化物与异腈进行氧化偶联来合成相应羧酸的重要方法。该反应具有广泛的底物范围和良好的官能团耐受性，能以中等至优异的产率得到相应的羧酸。
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