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含蒙脱石和氢氧化铝填料的高密度聚乙烯(HDPE)与聚对苯二甲酸丁二醇酯(PBT)复合材料的原子力显微镜(AFM)测量及测试性能

AFM Measurements and Testing Properties of HDPE and PBT Composites with Fillers in the Form of Montmorillonite and Aluminum Hydroxide.

作者信息

Bałaga Zbigniew, Gnatowski Adam, Kulesza Sławomir, Bramowicz Mirosław, Gwoździk Monika

机构信息

Faculty of Production Engineering and Materials Technology, Czestochowa University of Technology, Armii Krajowej Street 19, 42-201 Czestochowa, Poland.

Faculty of Mechanical Engineering and Computer Science, Czestochowa University of Technology, Armii Krajowej Street 21, 42-201 Czestochowa, Poland.

出版信息

Materials (Basel). 2022 Dec 7;15(24):8738. doi: 10.3390/ma15248738.

Abstract

This paper presents the effect of the addition of fillers such as aluminum hydroxide or montmorillonite on the structure and properties of polymers such as high-density polyethylene (HDPE) and polybutylene terephthalate (PBT). Both types of specimens were obtained by injection molding. X-ray diffraction examinations were performed on the materials obtained to determine the effect of the addition of the fillers used on the degree of crystallinity of the composites. The density and hardness of the composites were evaluated, and the static tensile test and the analysis of the structure parameters using atomic force microscopy (AFM) were also carried out. It was shown that the addition of powder fillers to polymers such as high-density polyethylene and polybutylene terephthalate affects the structure parameters such as surface roughness, mean grain size, anisotropy ratio, fractal dimension, the corner frequency of the composites, and mechanical properties such as Young's pseudo-modulus, average adhesion force, hardness, and tensile strength.

摘要

本文介绍了添加氢氧化铝或蒙脱石等填料对高密度聚乙烯(HDPE)和聚对苯二甲酸丁二醇酯(PBT)等聚合物结构和性能的影响。两种类型的试样均通过注塑成型获得。对所得材料进行了X射线衍射检查,以确定所用填料的添加对复合材料结晶度的影响。评估了复合材料的密度和硬度,并进行了静态拉伸试验以及使用原子力显微镜(AFM)对结构参数的分析。结果表明,向高密度聚乙烯和聚对苯二甲酸丁二醇酯等聚合物中添加粉末填料会影响结构参数,如表面粗糙度、平均晶粒尺寸、各向异性比、分形维数、复合材料的拐角频率,以及力学性能,如杨氏假模量、平均粘附力、硬度和拉伸强度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fcf4/9781561/ae070cc51b6d/materials-15-08738-g001.jpg

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