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改性磷酸钾镁水泥的耐高温性能

High-Temperature Resistance of Modified Potassium Magnesium Phosphate Cement.

作者信息

Yang Yuqi, Liu Yan, Yan Zizhuo, Chen Zhuoyi

机构信息

School of Civil Engineering, Changsha University of Science & Technology, Changsha 410114, China.

出版信息

Materials (Basel). 2022 Dec 15;15(24):8967. doi: 10.3390/ma15248967.

Abstract

To study the high-temperature mechanical properties of potassium magnesium phosphate cement mortar and the high-temperature resistance of its laminates. Potassium magnesium phosphate cement (MKPC) was prepared by using heavy-burning magnesium oxide and potassium dihydrogen phosphate as the main raw materials, borax as the retarder, and compounded with a certain amount of fly ash and silica fume. The effect of the mass ratio of magnesium to phosphorus (M:P), compounded fly ash and silica fume on the setting time and mechanical properties of MKPC was investigated. Furthermore, based on the better M:P, the compressive strength of MKPC mortar was studied after 3 h of constant temperature at 400 °C, 600 °C, and 800 °C, and the effect of fly ash and silica fume on the high-temperature resistance of MKPC was analyzed. The high-temperature resistance of MKPC was further evaluated by analyzing the temperature variation of potassium magnesium phosphate cement laminate during a constant temperature of 650 °C for 3 h. The results showed that the mechanical properties of potassium magnesium phosphate cement were influenced by different raw material ratios, and the mechanical properties of potassium magnesium phosphate cement were optimal when M:P was 2:1, fly ash was 5% and silica fume was 15%. The internal temperature of MKPC laminate increased slowly with time, and its high-temperature resistance was better.

摘要

研究磷酸钾镁水泥净浆的高温力学性能及其层压板的耐高温性能。以重烧氧化镁和磷酸二氢钾为主要原料,硼砂为缓凝剂,并复合一定量的粉煤灰和硅灰制备磷酸钾镁水泥(MKPC)。研究了镁磷质量比(M:P)、复合粉煤灰和硅灰对MKPC凝结时间和力学性能的影响。此外,基于较好的M:P,研究了MKPC净浆在400℃、600℃和800℃恒温3h后的抗压强度,并分析了粉煤灰和硅灰对MKPC耐高温性能的影响。通过分析磷酸钾镁水泥层压板在650℃恒温3h过程中的温度变化,进一步评估了MKPC的耐高温性能。结果表明,不同原料比例对磷酸钾镁水泥的力学性能有影响,当M:P为2:1、粉煤灰为5%、硅灰为15%时,磷酸钾镁水泥的力学性能最佳。MKPC层压板内部温度随时间缓慢升高,其耐高温性能较好。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/65a9/9783121/5fc769e62dc9/materials-15-08967-g001.jpg

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