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镁基胶凝材料进展的全面综述:水化、性能及在土壤稳定中的应用

A Comprehensive Review of Advances in Magnesium-Based Cementitious Materials: Hydration, Properties, and Applications in Soil Stabilization.

作者信息

Xu Qi, Chen Dongliang, Xiong Jian, He Xin, Dong Shengde, Ma Luxiang, Hai Chunxi, Zhou Yuan, Sun Yanxia

机构信息

College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China.

Department of Biological and Chemical Engineering, Agricultural School, Panzhihua University, Panzhihua 617000, China.

出版信息

Materials (Basel). 2025 Aug 13;18(16):3806. doi: 10.3390/ma18163806.

DOI:10.3390/ma18163806
PMID:40870126
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12387532/
Abstract

This review provides a comprehensive overview of the advancements in magnesium-based cementitious materials (MBCMs), including magnesium oxychloride cementitious material (MOC), magnesium oxysulfate cementitious material (MOS), and magnesium phosphate cementitious material (MPC). The hydration processes and products, performance characteristics, and applications in soil stabilization are systematically discussed. Key findings reveal that MOC exhibits rapid strength development and excellent thermal stability, while MOS demonstrates improved water resistance and mechanical properties. MPC is highlighted for its effectiveness in the immobilization of heavy metals. The environmental impact of MBCMs is also evaluated, highlighting their potential for sustainable development in civil engineering applications. The primary issues and challenges for MBCMs in soil curing include the insufficient stability of hydration products and inadequate understanding of curing mechanisms, leading to variable material properties and difficulties in precisely controlling the curing effects in practical engineering. Additionally, the complex composition of MBCMs and the highly variable characteristics of natural soils result in significant differences in curing effectiveness under different conditions, restricting their application scope and posing risks to project costs and quality stability.

摘要

本综述全面概述了镁基胶凝材料(MBCMs)的进展,包括氯氧镁胶凝材料(MOC)、硫氧镁胶凝材料(MOS)和磷酸镁胶凝材料(MPC)。系统地讨论了其水化过程和产物、性能特点以及在土壤稳定化中的应用。主要研究结果表明,MOC表现出快速的强度发展和优异的热稳定性,而MOS则具有更好的耐水性和力学性能。MPC因其在固定重金属方面的有效性而受到关注。还评估了MBCMs对环境的影响,突出了它们在土木工程应用中可持续发展的潜力。MBCMs在土壤固化中的主要问题和挑战包括水化产物稳定性不足以及对固化机理的理解不够,导致材料性能多变,在实际工程中难以精确控制固化效果。此外,MBCMs的复杂组成和天然土壤高度可变的特性导致不同条件下固化效果存在显著差异,限制了它们的应用范围,并给项目成本和质量稳定性带来风险。

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