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用于水净化的具有强耐酸碱腐蚀性的双层多壁碳纳米管@超支化聚硅氧烷光热纸

Double-Layer MWCNTs@HPPS Photothermal Paper for Water Purification with Strong Acid-Alkali Corrosion Resistance.

作者信息

Gao Yuan, Jin Guoqing, Wang Shuaishuai, Lyu Lihua, Wei Chunyan, Zhou Xinghai

机构信息

School of Textile and Materials Engineering, Dalian Polytechnic University, Dalian 116034, China.

Shandong Chambroad Holding Group Co., Ltd., Binzhou 256500, China.

出版信息

Membranes (Basel). 2022 Nov 29;12(12):1208. doi: 10.3390/membranes12121208.

Abstract

Solar-driven interfacial evaporation technology has been identified as a promising method to relieve the global water crisis, and it is particularly important to design an ideal structure of the solar thermal conversion evaporation device. In this paper, hydrophilic polyphenylene sulfide (HPPS) paper with loose structure and appropriate water transmission performance was designed as the based-material, and multi-walled carbon nanotubes (MWCNTs) layer with excellent photothermal conversion performance was constructed to realize the high-efficiency solar-driven evaporation. Under tail swabbing mode, the cold evaporation surface on the back of the evaporator greatly improved the evaporation rate, cut off the heat transfer channel to bulk water, and achieved the maximum evaporation rate of 1.23 L/m·h. Ethyl cellulose (EC) was introduced to adjust the water supply performance of HPPS layer, and a large specific surface area of cold evaporation was obtained, thus improving the water evaporation rate. In the simulation experiment of seawater desalination and dye wastewater treatment, it showed good water purification capacity and acid/alkali-resistance, which had great practical application significance.

摘要

太阳能驱动的界面蒸发技术已被视为缓解全球水危机的一种有前景的方法,设计太阳能热转换蒸发装置的理想结构尤为重要。本文设计了具有疏松结构和适当输水性能的亲水性聚苯硫醚(HPPS)纸作为基材,并构建了具有优异光热转换性能的多壁碳纳米管(MWCNTs)层,以实现高效太阳能驱动蒸发。在尾拭模式下,蒸发器背面的冷蒸发表面极大地提高了蒸发速率,切断了与大量水体的传热通道,实现了1.23 L/m·h的最大蒸发速率。引入乙基纤维素(EC)来调节HPPS层的供水性能,获得了大比表面积的冷蒸发,从而提高了水蒸发速率。在海水淡化和染料废水处理的模拟实验中,其表现出良好的水净化能力和耐酸/碱性,具有重大的实际应用意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca08/9782072/9dc8ffbbb682/membranes-12-01208-g001.jpg

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