Department of Materials Science and Engineering, Chonnam National University, Gwangju 61186, Republic of Korea.
Department of Prosthodontics, Dental Science Research Institute, School of Dentistry, Chonnam National University, Gwangju 61186, Republic of Korea.
Molecules. 2022 Dec 7;27(24):8664. doi: 10.3390/molecules27248664.
Recently, a novel electrochemical regulation associated with a deposition/dissolution reaction on an electrode surface has been proven to show superiority in large-scale energy storage systems (ESSs). Hence, in the search for high-performance electrodes showcasing these novel regulations, we utilized a low-cost ZnO microsphere electrode to construct aqueous rechargeable batteries (ARBs) that supplied a harvestable and storable charge through electrochemical deposition/dissolution via a reversible manganese oxidation reaction (MOR)/manganese reduction reaction (MRR), respectively, induced by the inherent formation/dissolution of zinc basic sulfate in a mild aqueous electrolyte solution containing 2 M ZnSO and 0.2 M MnSO.
最近，一种新型的电化学调控与电极表面上的沉积/溶解反应相关联，已被证明在大规模储能系统（ESSs）中具有优势。因此，在寻找具有这些新型调控的高性能电极的过程中，我们利用低成本的 ZnO 微球电极构建了水系可充电电池（ARBs），通过在含有 2 M ZnSO 和 0.2 M MnSO 的温和水溶液电解质中固有的 Zn 基硫酸盐的形成/溶解，分别通过电化学沉积/溶解诱导可收获和可存储的电荷，该过程分别通过可逆的锰氧化反应（MOR）/锰还原反应（MRR）实现。
