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具有类芬顿催化降解土霉素性能的还原氧化石墨烯包覆的铜铁氧体

Reduced Graphene Oxide-Coated CuFeO with Fenton-like Catalytic Degradation Performance for Terramycin.

作者信息

Wang Liping, Liu Gonghao, Zhang Mingyu, Luo Kun, Pang Ya

机构信息

College of Materials and Environmental Engineering, Changsha University, Changsha 410022, China.

State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China.

出版信息

Nanomaterials (Basel). 2022 Dec 9;12(24):4391. doi: 10.3390/nano12244391.

Abstract

A novel Fenton-like catalyst made of reduced graphene oxide-coated CuFeO (rGO-coated CuFeO) was synthesized by the hydrothermal reaction method to remove terramycin from aqueous solutions. The catalytic degradation performance of rGO-coated CuFeO for terramycin was verified with HO activation. The characterization reveals that rGO-coated CuFeO has a micro- and mesoporous structure, with groups such as C=C/C-C, CH-CO, and HO-C=O found on the surface. The Fenton-like catalytic degradation of terramycin by rGO-coated CuFeO was in line with the pseudo-second-order kinetic model, and the elevated temperature accelerated the reaction. Terramycin was catalytically degraded by rGO-coated CuFeO in two steps: terramycin was first adsorbed by rGO, and then Fenton-like degradation took place on its surface. This research presents new insight into the design and fabrication of Fenton-like catalysts with enhanced performance.

摘要

通过水热反应法合成了一种新型的由还原氧化石墨烯包覆的CuFeO(rGO包覆的CuFeO)类芬顿催化剂,用于从水溶液中去除土霉素。通过HO活化验证了rGO包覆的CuFeO对土霉素的催化降解性能。表征结果表明,rGO包覆的CuFeO具有微孔和介孔结构,表面存在C=C/C-C、CH-CO和HO-C=O等基团。rGO包覆的CuFeO对土霉素的类芬顿催化降解符合准二级动力学模型,升高温度加速了反应。土霉素被rGO包覆的CuFeO催化降解分两步进行:土霉素首先被rGO吸附,然后在其表面发生类芬顿降解。本研究为设计和制备性能增强的类芬顿催化剂提供了新的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef0c/9781562/79c349351e23/nanomaterials-12-04391-g001.jpg

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