Department of Mechanical & Electrical Engineering, Xiamen University, Xiamen361005, P. R. China.
Fujian Micro/Nano Manufacturing Engineering Technology Research Center, Xiamen University, Xiamen361102, P. R. China.
ACS Appl Mater Interfaces. 2023 Jan 11;15(1):2172-2182. doi: 10.1021/acsami.2c18611. Epub 2022 Dec 27.
In situ temperature monitoring of curved high-temperature components in extreme environments is challenging for a variety of applications in fields such as aero engines and gas turbines. Recently, extrusion-based direct ink writing (DIW) has been utilized to fabricate platinum (Pt) resistance temperature detectors (RTDs). However, the current Pt RTD prepared by DIW technology suffers from a limited temperature range and poor high-temperature stability. Here, DIW technology and yttria-stabilized zirconia (YSZ)-modified precursor ceramic film packaging have been used to build a Pt RTD with high-temperature resistance, small disturbance, and high stability. The results indicate that the protective layer formed by the liquid phase anchors the Pt particles and reduces the agglomeration and volatilization of the Pt sensitive layer at high temperature. Attributed to the SiCN/YSZ protective layer, the temperature resistance curve of the Pt RTD in the range of 50-800 °C has little deviation from the fitting curve, and the fitting correlation coefficient is above 0.9999. Interestingly, the Pt RTD also has high repeatability and stability. The high temperature resistance drift rate is only 0.05%/h after 100 h of long-term testing at 800 °C and can withstand butane flame up to ∼1300 °C without damage. Moreover, the Pt RTD can be conformally deposited on the outer ring of aerospace bearings by DIW technology and then realize on-site, nondestructive, and real-time monitoring of bearing temperature. The fabricated Pt RTD shows great potential for high-temperature applications, and the novel technology proposed provides a feasible pathway for temperature monitoring of aeroengine internal curved hot-end components.
在航空发动机和燃气轮机等领域的各种应用中,对极端环境下弯曲高温部件的原位温度监测具有挑战性。最近,基于挤出的直接墨水书写(DIW)已被用于制造铂(Pt)电阻温度探测器(RTD)。然而,目前通过 DIW 技术制备的 Pt RTD 存在温度范围有限和高温稳定性差的问题。在这里,DIW 技术和氧化钇稳定氧化锆(YSZ)改性前体陶瓷膜封装已被用于构建具有耐高温、小干扰和高稳定性的 Pt RTD。结果表明,液相形成的保护层固定了 Pt 颗粒,减少了高温下 Pt 敏感层的团聚和挥发。由于 SiCN/YSZ 保护层的存在,Pt RTD 在 50-800°C 范围内的温度阻力曲线与拟合曲线几乎没有偏差,拟合相关系数高于 0.9999。有趣的是,Pt RTD 还具有高重复性和稳定性。在 800°C 下经过 100 小时的长期测试,高温阻力漂移率仅为 0.05%/h,并且可以承受高达约 1300°C 的丁烷火焰而不会损坏。此外,Pt RTD 可以通过 DIW 技术在航空航天轴承的外环上进行共形沉积,然后实现轴承温度的现场、无损和实时监测。所制造的 Pt RTD 具有很大的高温应用潜力,所提出的新技术为航空发动机内部弯曲热端部件的温度监测提供了可行的途径。