Triangular Heteroporous Covalent Organic Framework via a K-Shaped "Two-in-One" Monomer: Targeted Synthesis and Selective Removal of Organic Pollutants.

Covalent organic frameworks (COFs) have attracted increasing research interest due to their intriguing topological structures and fascinating properties. Diverse COFs with different shapes and sizes are developed by the design of appropriate building blocks. However, the heteroporous COFs to date are still in their infancy due to the relatively limited configuration of precursors. Herein, it is ingeniously designed and synthesized a new K-shaped "two-in-one" building unit (3',6'-bis(4-(5,5-dimethyl-1,3-dixoan-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diamine, BPTD), thus realizing the construction of triangular dual microporous COF (BPTD-COF) via self-polycondensation of the K-shaped monomer. The super micropore (0.76 nm) of BPTD-COF endows the higher density of amine activity sites, while the other aperture size (1.35 nm) meets the need for accommodating cationic dyes (rhodamine B, methylene blue), thus BPTD-COF displays a distinctive selective adsorption for cationic dyes with good reusability.