Ma Xiang, Bhattacharya Saurav, Nisar Talha, Müller Anja B, Wagner Veit, Kuhnert Nikolai, Kortz Ulrich
School of Science, Jacobs University, Campus Ring 1, 28759, Bremen, Germany.
Chem Commun (Camb). 2023 Jan 19;59(7):904-907. doi: 10.1039/d2cc05699b.
We report on the first example of a Pd-containing polyoxopalladate(II). The discrete mixed-valent polyoxopalladate(IV/II), [PdPdII6O((CH)AsO)], comprising a central Pd ion that is surrounded by a six-membered Pd-oxo ring capped by six dimethylarsinate groups, was synthesized and structurally characterized in the solid state, in solution and in the gas phase by multiple analytical techniques.
我们报道了首例含钯的多氧钯酸盐（II）。通过多种分析技术，合成并在固态、溶液和气相中对离散的混合价多氧钯酸盐（IV/II）[PdPdII6O((CH)AsO)]进行了结构表征，该化合物包含一个中心钯离子，其周围是一个由六个二甲基砷酸根基团封端的六元钯-氧环。
