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金属有机框架对水环境中砷吸附过程近期成果的简要综述:基于动力学、等温线和热力学行为的分类

A Brief Review of Recent Results in Arsenic Adsorption Process from Aquatic Environments by Metal-Organic Frameworks: Classification Based on Kinetics, Isotherms and Thermodynamics Behaviors.

作者信息

Samimi Mohsen, Zakeri Mozhgan, Alobaid Falah, Aghel Babak

机构信息

Department of Chemical Engineering, Faculty of Engineering, Kermanshah University of Technology, Kermanshah 6715685420, Iran.

Department of Chemical Engineering, Faculty of Engineering, University of Sistan and Baluchestan, Zahedan 9816745639, Iran.

出版信息

Nanomaterials (Basel). 2022 Dec 23;13(1):60. doi: 10.3390/nano13010060.

Abstract

In nature, arsenic, a metalloid found in soil, is one of the most dangerous elements that can be combined with heavy metals. Industrial wastewater containing heavy metals is considered one of the most dangerous environmental pollutants, especially for microorganisms and human health. An overabundance of heavy metals primarily leads to disturbances in the fundamental reactions and synthesis of essential macromolecules in living organisms. Among these contaminants, the presence of arsenic in the aquatic environment has always been a global concern. As (V) and As (III) are the two most common oxidation states of inorganic arsenic ions. This research concentrates on the kinetics, isotherms, and thermodynamics of metal-organic frameworks (MOFs), which have been applied for arsenic ions uptake from aqueous solutions. This review provides an overview of the current capabilities and properties of MOFs used for arsenic removal, focusing on its kinetics and isotherms of adsorption, as well as its thermodynamic behavior in water and wastewater.

摘要

在自然界中,砷是一种存在于土壤中的类金属,是可与重金属结合的最危险元素之一。含有重金属的工业废水被认为是最危险的环境污染物之一,尤其是对微生物和人类健康而言。过量的重金属主要会导致生物体基本反应和必需大分子合成受到干扰。在这些污染物中,砷在水环境中的存在一直是全球关注的问题。砷(V)和砷(III)是无机砷离子最常见的两种氧化态。本研究集中于金属有机框架材料(MOFs)对水溶液中砷离子的吸附动力学、等温线和热力学。本综述概述了用于去除砷的MOFs的当前性能和特性,重点关注其吸附动力学和等温线,以及其在水和废水中的热力学行为。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd24/9823661/af331e88c2ac/nanomaterials-13-00060-g001.jpg

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