Salen、salan 和 salalen 锌(II)配合物与 HS 的相互作用：时间分辨荧光应用。
Salen, salan and salalen zinc(II) complexes in the interaction with HS: time-resolved fluorescence applications.
机构信息
Dipartimento di Chimica e Biologia "Adolfo Zambelli", Università degli Studi di Salerno, Via Giovanni Paolo II, 132, 84084, Fisciano (SA), Italy.
Institute of Food Science, CNR Italy, 83100 Avellino, Italy.
出版信息
Dalton Trans. 2023 Jan 31;52(5):1357-1365. doi: 10.1039/d2dt03730k.
In the current work we investigate the route of interaction of a newly synthesized family of zinc complexes with HS by a plethora of different spectroscopic techniques. A computational analysis on the time dependent density functional theory (TD-DFT) level explored the overall fluorescence properties of the title complexes and their different fluorescence responses to HS. Time-resolved fluorescence experiments were also performed and highlight the great potential of the current systems to be implemented as HS fluorescent sensors.
在当前的工作中，我们通过多种不同的光谱技术研究了新合成的一系列锌配合物与 HS 的相互作用途径。在时间依赖密度泛函理论（TD-DFT）水平上的计算分析探讨了标题配合物的整体荧光性质及其对 HS 的不同荧光响应。还进行了时间分辨荧光实验，突出了当前系统作为 HS 荧光传感器的巨大潜力。
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