使用 Ag/CeO 纳米复合材料实现可见光驱动的 CO 与醇的反应：在温和条件下首次通过光化学反应合成直链碳酸酯。
Visible-light driven reaction of CO with alcohols using a Ag/CeO nanocomposite: first photochemical synthesis of linear carbonates under mild conditions.
机构信息
Chemical & Material Sciences Division, CSIR-Indiam Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India.
Academy of Scientific and Innovative Research, Ghaziabad-201002, India.
出版信息
Chem Commun (Camb). 2023 Jan 31;59(10):1313-1316. doi: 10.1039/d2cc05152d.
PMID:36636985
Abstract
The first photochemical synthesis of linear carbonates from the reaction of CO with alcohols using a silver-doped ceria nanocomposite at room temperature under visible light irradiation is described. DFT calculations suggested the electron transfer from Ag 4d states to Ce 4f states in the composite for the photoreaction.
摘要
首次描述了在室温下可见光照射下，使用掺银氧化铈纳米复合材料，通过 CO 与醇的反应，光化学合成线性碳酸酯。DFT 计算表明，在光反应中，电子从复合体系中的 Ag 4d 态转移到 Ce 4f 态。
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