Chemical & Material Sciences Division, CSIR-Indiam Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India.
Academy of Scientific and Innovative Research, Ghaziabad-201002, India.
Chem Commun (Camb). 2023 Jan 31;59(10):1313-1316. doi: 10.1039/d2cc05152d.
The first photochemical synthesis of linear carbonates from the reaction of CO with alcohols using a silver-doped ceria nanocomposite at room temperature under visible light irradiation is described. DFT calculations suggested the electron transfer from Ag 4d states to Ce 4f states in the composite for the photoreaction.
首次描述了在室温下可见光照射下，使用掺银氧化铈纳米复合材料，通过 CO 与醇的反应，光化学合成线性碳酸酯。DFT 计算表明，在光反应中，电子从复合体系中的 Ag 4d 态转移到 Ce 4f 态。
