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废弃聚氨酯泡沫的处置、回收与管理综述:未来之路

Review on disposal, recycling and management of waste polyurethane foams: A way ahead.

作者信息

Banik Jyotiparna, Chakraborty Debdyuti, Rizwan Mohammed, Shaik Aabid Hussain, Chandan Mohammed Rehaan

机构信息

Colloids and Polymers Research Group, School of Chemical Engineering, Vellore Institute of Technology, Vellore, TN, India.

出版信息

Waste Manag Res. 2023 Jun;41(6):1063-1080. doi: 10.1177/0734242X221146082. Epub 2023 Jan 16.

Abstract

With the burning issue of air, land and water pollution, the premonition of looking forward towards a future devoid of any kind of oil and gas reserves has caused a paradigm shift towards recycling, recovery of any synthetic polymer and also to dispose them off environmentally. Among them are plastics such as polyethylene terephthalate and poly vinyl chloride. Polyurethane (PU) is also under the scanner to dispose of or recycle it environmentally and sustainably. PU is at present the sixth most utilized polymer all over the world with a production of nearly 18 million tonnes per annum, which roughly estimates a daily production of PU products of greater than a million of cubic metres. Its thermostable nature is one of the major reasons for its higher preference over other polymers. This review article discusses the current disposal and technologies available to recycle waste PU foams and also sheds some light on some additional work being done in the field to upgrade the existing technology. Interestingly, some methods mentioned here are probably undergoing scale-up trials runs by now. Currently, the most researched and studied ones are mechanical recycling and glycolysis. But microbial and enzymatic disposal methods can be turned into full-scale industrial recycling processes in the near future. Additionally, we can see an archetypal shift from traditional oil-based sources to the agrarian sources.

摘要

随着空气、土地和水污染这一紧迫问题的出现,对未来没有任何油气储备的预感到来,引发了向回收利用、回收任何合成聚合物以及以环保方式处理它们的范式转变。其中包括聚对苯二甲酸乙二酯和聚氯乙烯等塑料。聚氨酯(PU)也在接受审视,以实现环保和可持续的处理或回收利用。PU目前是全球第六大使用量最多的聚合物,年产量近1800万吨,粗略估计每天生产的PU产品超过100万立方米。其热稳定性质是其比其他聚合物更受青睐的主要原因之一。这篇综述文章讨论了目前可用于回收废旧PU泡沫的处理方法和技术,还介绍了该领域为改进现有技术所做的一些其他工作。有趣的是,这里提到的一些方法目前可能正在进行扩大规模的试验。目前,研究最多的是机械回收和醇解。但微生物和酶处理方法在不久的将来可以转变为大规模工业回收工艺。此外,我们可以看到从传统石油基来源向农业来源的典型转变。

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