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一种糖基化修饰的共价聚合物抑尘剂的合成与性能测定

Synthesis and performance determination of a glycosylated modified covalent polymer dust suppressant.

作者信息

Dong Hui, Yu Haiming, Xu Rongxiao, Ye Yuxi, Wang Ru, Cheng Weimin

机构信息

College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China; State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology, Shandong University of Science and Technology, Qingdao 266590, China.

College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China; State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology, Shandong University of Science and Technology, Qingdao 266590, China.

出版信息

Int J Biol Macromol. 2023 Mar 15;231:123287. doi: 10.1016/j.ijbiomac.2023.123287. Epub 2023 Jan 15.

Abstract

Traditional polymer dust suppressants are limited due to environmental pollution, while polymer gels have attracted attention due to the advantages of environmental protection and good biocompatibility. The purpose of this research is to prepare a new type of dust suppressant with a gel network structure, which was synthesized from soybean protein isolate and glycosylated with xanthan gum. The experimental results showed that the product obtained by reacting 0.2 % xanthan gum and 0.1 % soybean protein isolate at 90 °C for 4 h has the best binding effect on coal dust, and the coal husk hardness can reach 83 HA. The microscopic reaction and structure of the product were analyzed by infrared spectroscopy, X-ray diffractometer, and scanning electron microscope, and the results revealed the structural change and specific reaction process of the product. In addition, through molecular dynamics simulation, the dust suppression effect was confirmed and the mechanism of action between dust suppressant and coal was revealed. The performance test of the dust suppressant showed that its viscosity is 23.4 mPa·s, the contact angle at 1 s is 10.01°, the PM10 dust suppression efficiency can reach 98.10 %, the water retention is 44.44 % higher than that of water, and thermal stability is improved.

摘要

传统的聚合物抑尘剂因环境污染而受到限制,而聚合物凝胶因其环保和良好的生物相容性优势而备受关注。本研究的目的是制备一种具有凝胶网络结构的新型抑尘剂,它由大豆分离蛋白合成并用黄原胶进行糖基化。实验结果表明,在90℃下将0.2%的黄原胶与0.1%的大豆分离蛋白反应4小时得到的产物对煤尘具有最佳的粘结效果,煤壳硬度可达83 HA。通过红外光谱、X射线衍射仪和扫描电子显微镜对产物的微观反应和结构进行了分析,结果揭示了产物的结构变化和具体反应过程。此外,通过分子动力学模拟,证实了抑尘效果并揭示了抑尘剂与煤之间的作用机理。抑尘剂的性能测试表明,其粘度为23.4 mPa·s,1 s时的接触角为10.01°,PM10抑尘效率可达98.1%,保水性比水高44.44%,热稳定性得到提高。

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