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关于反应性增容丙烯酸基复合材料/聚酰胺(PA)-12的热板焊接

On the Hot-Plate Welding of Reactively Compatibilized Acrylic-Based Composites/Polyamide (PA)-12.

作者信息

Perrin Henri, Bodaghi Masoud, Berthé Vincent, Klein Sébastien, Vaudemont Régis

机构信息

Luxembourg Institute of Science and Technology (LIST), 5, rue Bommel, L-4940 Hautcharage, Luxembourg.

出版信息

Materials (Basel). 2023 Jan 10;16(2):691. doi: 10.3390/ma16020691.

Abstract

Joining of dissimilar thermoplastics and their composites is a challenge for thermal welding techniques due to different melting points. Reactive welding with an auxiliary functional material can offer the clear opportunities to develop joining processes due to robustness to joining dissimilar thermoplastic polymers and their composites. The current study employed reactive compatibilization to offer the possibility of joining an acrylic-based glass fiber composite to polyamide (PA)-12 by applying a hot-tool welding technique. For this purpose, composite plates are fabricated by a typical vacuum infusion and thin layer thermoplastic films are formed by a thermostamping of PA12 granules. Subsequently, the reactive welding of the interposed PA12 sheet and Elium-GMA-Glass composite is conducted by hot-plate welding. A glycidyl methacrylate (GMA) as a compatibilizing agent is copolymerized with methyl methacrylate Elium resin. During the hot-tool welding process of dissimilar thermoplastic material, GMA can react with the polyamide end groups. The heat distribution at the Elium GMA/PA-12 interface is responsible for obtaining a strong joint. This study focuses on the functionality of the compatibilizer on the welding of acrylic-based composites with polyamide (PA)-12 while varying the assembly temperature. The flatwise tensile test proved the effectiveness of GMA on the interface bounding. The excellent bounding incompatible polymers Elium resin (PMMA) and PA12 was achieved at 200 °C.

摘要

由于熔点不同,将异种热塑性塑料及其复合材料连接起来对热焊接技术而言是一项挑战。使用辅助功能材料进行反应焊接,由于其在连接异种热塑性聚合物及其复合材料方面的稳健性,为开发连接工艺提供了明显的机会。当前的研究采用反应增容法,通过应用热工具焊接技术,实现了将丙烯酸基玻璃纤维复合材料与聚酰胺(PA)-12连接的可能性。为此,通过典型的真空灌注法制造复合板,并通过对PA12颗粒进行热压印形成热塑性薄膜薄层。随后,通过热板焊接对插入的PA12片材和Elium-GMA-玻璃复合材料进行反应焊接。作为增容剂的甲基丙烯酸缩水甘油酯(GMA)与甲基丙烯酸甲酯Elium树脂共聚。在异种热塑性材料的热工具焊接过程中,GMA可与聚酰胺端基发生反应。Elium GMA/PA-12界面处的热分布有助于获得牢固的接头。本研究聚焦于在改变组装温度的情况下,增容剂对丙烯酸基复合材料与聚酰胺(PA)-12焊接的作用。平面拉伸试验证明了GMA在界面结合方面的有效性。在200°C时实现了不相容聚合物Elium树脂(PMMA)和PA12之间的优异结合。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd79/9863318/cf9c4984847f/materials-16-00691-g001.jpg

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