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关于向丙烯酸基不可熔树脂中添加多功能甲基丙烯酸酯单体以实现丙烯酸基玻璃纤维复合材料的可焊接性

On the Addition of Multifunctional Methacrylate Monomers to an Acrylic-Based Infusible Resin for the Weldability of Acrylic-Based Glass Fibre Composites.

作者信息

Perrin Henri, Bodaghi Masoud, Berthé Vincent, Vaudemont Régis

机构信息

Luxembourg Institute of Science and Technology (LIST), 5, rue Bommel, L-4940 Hautcharage, Luxembourg.

出版信息

Polymers (Basel). 2023 Feb 28;15(5):1250. doi: 10.3390/polym15051250.

Abstract

The melt strength of Elium acrylic resin is an important factor to ensure limited fluid flow during welding. To provide Elium with a suitable melt strength via a slight crosslink, this study examines the effect of two dimethacrylates, namely butanediol-di-methacrylate (BDDMA) and tricyclo-decane-dimethanol-di-methacrylate (TCDDMDA), on the weldability of acrylic-based glass fibre composites. The resin system impregnating a five-layer woven glass preform is a mixture of Elium acrylic resin, an initiator, and each of the multifunctional methacrylate monomers in the range of 0 to 2 parts per hundred resin (phr). Composite plates are manufactured by vacuum infusion (VI) at an ambient temperature and welded by using the infrared (IR) welding technique. The mechanical thermal analysis of the composites containing multifunctional methacrylate monomers higher than 0.25 phr shows a very little strain for the temperature range of 50 °C to 220 °C. The quantity of 0.25 phr of both of the multifunctional methacrylate monomers in the Elium matrix improves the maximum bound shear strength of the weld by 50% compared to those compositions without the multifunctional methacrylate monomers.

摘要

Elium丙烯酸树脂的熔体强度是确保焊接过程中流体流动受限的一个重要因素。为了通过轻微交联赋予Elium合适的熔体强度,本研究考察了两种二甲基丙烯酸酯,即丁二醇二甲基丙烯酸酯(BDDMA)和三环癸烷二甲基丙烯酸酯(TCDDMDA)对丙烯酸基玻璃纤维复合材料可焊性的影响。浸渍五层玻璃编织预成型件的树脂体系是Elium丙烯酸树脂、引发剂以及每百份树脂(phr)0至2份范围内的各多功能甲基丙烯酸酯单体的混合物。复合板在环境温度下通过真空灌注(VI)制造,并使用红外(IR)焊接技术进行焊接。对含有高于0.25 phr多功能甲基丙烯酸酯单体的复合材料进行的机械热分析表明,在50℃至220℃的温度范围内应变非常小。与不含多功能甲基丙烯酸酯单体的组合物相比,Elium基体中0.25 phr的两种多功能甲基丙烯酸酯单体可使焊接的最大结合剪切强度提高50%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/988f/10007228/30af0db09458/polymers-15-01250-g005.jpg

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