Xie Xiaogeng, Fan Junqi, Guo Peng, Huang Haoliang, Hu Jie, Wei Jiangxiong
School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China.
Research Institute for National Defense Engineering of Academy of Military Sciences PLA China, Luoyang 471023, China.
Materials (Basel). 2023 Jan 11;16(2):700. doi: 10.3390/ma16020700.
Both the discrete and continuous particle packing models are used to design UHPC, but the influences of a water film covering the particle surfaces on the compactness of the particle system were not considered in these models. In fact, the water film results in a certain distance between solid particles (DSP), which affects the compactness of the particle system, especially for cementitious materials with small particle sizes. In the present study, the mixture design method for UHPC was proposed based on the Fuller distribution model modified using the DSP. Then, the components of cementitious materials and aggregates were optimized, and the UHPC matrices with high solid concentrations were obtained. The results showed that the solid concentration, slump flow, and compressive strength of the UHPC matrix reached 77.1 vol.%, 810 mm, and 162.0 MPa, respectively. By replacing granulated blast furnace slag (GBFS) with quartz powder (QP), the flexural strength of the UHPC matrix was increased without reducing its compressive strength. When the steel fiber with a volume fraction of 1.5% was used, the slump flow, compressive strength, tensile strength, and flexural strength of the UHPC reached 740 mm, 175.6 MPa, 9.7 MPa, and 22.8 MPa, respectively. After 500 freeze-thaw cycles or 60 dry-wet cycles under sulfate erosion, the mechanical properties did not deteriorate. The chloride diffusion coefficients in UHPCs were lower than 3.0 × 10 m/s, and the carbonation depth of each UHPC was 0 mm after carbonization for 28 days. The UHPCs presented ideal workability, mechanical properties, and durability, demonstrating the validity of the method proposed for UHPC design.
离散和连续颗粒堆积模型都被用于超高性能混凝土(UHPC)的设计,但这些模型未考虑覆盖颗粒表面的水膜对颗粒系统密实度的影响。事实上,水膜导致固体颗粒之间存在一定距离(DSP),这会影响颗粒系统的密实度,尤其是对于小粒径胶凝材料。在本研究中,基于使用DSP修正的富勒分布模型提出了UHPC的配合比设计方法。然后,对胶凝材料和骨料的组分进行了优化,得到了高固体浓度的UHPC基体。结果表明,UHPC基体的固体浓度、坍落流动度和抗压强度分别达到77.1体积%、810毫米和162.0兆帕。用石英粉(QP)替代粒化高炉矿渣(GBFS),在不降低UHPC基体抗压强度的情况下提高了其抗弯强度。当使用体积分数为1.5%的钢纤维时,UHPC的坍落流动度、抗压强度、抗拉强度和抗弯强度分别达到740毫米、175.6兆帕、9.7兆帕和22.8兆帕。经过500次冻融循环或在硫酸盐侵蚀下60次干湿循环后,力学性能没有恶化。UHPC中的氯离子扩散系数低于3.0×10⁻¹²米²/秒,碳化28天后各UHPC的碳化深度为0毫米。这些UHPC表现出理想的工作性能、力学性能和耐久性,证明了所提出的UHPC设计方法的有效性。