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还原氧化石墨烯/铜@铁铝酸盐复合材料的合成及其在电磁微波吸收涂层中的应用。

Synthesis of RGO/Cu@ FeAlO Composites and Its Applications in Electromagnetic Microwave Absorption Coatings.

作者信息

Chu Zhenhua, Deng Wenxing, Xu Jingxiang, Wang Fang, Zhang Zheng, Hu Qingsong

机构信息

Shanghai Engineering Research Center of Hadal Science and Technology, College of Engineering, Shanghai Ocean University, Shanghai 201306, China.

出版信息

Materials (Basel). 2023 Jan 12;16(2):740. doi: 10.3390/ma16020740.

Abstract

In order to satisfy the requirements of wide frequency bands, the lightweight and strong absorption for the electromagnetic wave absorbing materials, a uniform mixture of FeAlO with RGO/Cu (reduction graphene oxide, RGO) was obtained by the mechanical mixing method, and composite coating was obtained by plasma spraying. The addition of RGO/Cu into FeAlO is conducive to improve the dielectric properties and the impedance matching performance of spinel. When the RGO/Cu composite powders are doped by 10 wt.%, the reflection loss at 15 GHz is -16 dB and the absorption bandwidth is 2 GHz, indicating that the composite material has potential application value in the field of high-frequency wave absorption. The research on the electromagnetic wave absorption mechanism shows that its superior wave absorption performance is determined by the synergistic effect of multiple loss mechanisms such as interfacial polarization, dipole relaxation, natural resonance, exchange resonance, and eddy current loss.

摘要

为了满足宽频带、轻质且对电磁波吸收材料有强吸收性能的要求,通过机械混合法获得了FeAlO与RGO/Cu(还原氧化石墨烯,RGO)的均匀混合物,并通过等离子喷涂获得了复合涂层。向FeAlO中添加RGO/Cu有利于改善尖晶石的介电性能和阻抗匹配性能。当RGO/Cu复合粉末掺杂量为10 wt.%时,在15 GHz处的反射损耗为-16 dB,吸收带宽为2 GHz,表明该复合材料在高频吸波领域具有潜在的应用价值。对电磁波吸收机制的研究表明,其优异的吸波性能是由界面极化、偶极弛豫、自然共振、交换共振和涡流损耗等多种损耗机制的协同效应决定的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/403b/9860893/4c4198e69991/materials-16-00740-g001.jpg

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