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锚定在还原氧化石墨烯纳米片上的镍锰氧化物:一种新型高性能微波吸收材料。

NiMnO Anchored on Reduced Graphene Oxide Nanosheets: A New High-Performance Microwave Absorbing Material.

作者信息

Zhang Pin, Yao Yao, Zhou Wenke, Liu Yawen, Cao Xiaowei, Zhang Zhi

机构信息

Research Center for Camouflage Engineering, The Army Engineering University of PLA, Nanjing 210007, China.

State Key Laboratory for Disaster Prevention & Mitigation of Explosion & Impact, The Army Engineering University of PLA, Nanjing 210007, China.

出版信息

Nanomaterials (Basel). 2022 Mar 26;12(7):1089. doi: 10.3390/nano12071089.

Abstract

With the increasing influence of electromagnetic radiation on precision instruments and organisms, there is an urgent need for research on lightweight and high-strength electromagnetic wave absorbing materials. This study has probed into a new composite absorbing material based on reduced graphene oxide (rGO)-NiMnO, where the like-core-shell NiMnO is anchored on the rGO nanosheets to significantly improve the electromagnetic wave dissipation ability of the composite material using the inter-component dipole polarization and interface polarization. At the same time, NiMnO can effectively adjust the impedance matching ratio of rGO so that electromagnetic waves can effectively enter the absorbing material. At a thickness of 3.73 mm, the maximum absorption strength of rGO-NiMnO reaches -61.4 dB at 6.6 GHz; at a thickness of 2.5 mm, the adequate absorption bandwidth is 10.04-18.00 GHz, achieving a full coverage for the Ku band. As a new option for preparing lightweight and broadband electromagnetic wave absorbing materials, rGO-NiMnO is an ideal material for electromagnetic wave protection.

摘要

随着电磁辐射对精密仪器和生物体的影响日益增大,迫切需要开展对轻质高强度电磁波吸收材料的研究。本研究探究了一种基于还原氧化石墨烯(rGO)-NiMnO的新型复合吸收材料,其中类核壳结构的NiMnO锚定在rGO纳米片上,利用组分间的偶极极化和界面极化显著提高了复合材料的电磁波耗散能力。同时,NiMnO能够有效调节rGO的阻抗匹配率,使电磁波能够有效进入吸收材料。在厚度为3.73 mm时,rGO-NiMnO在6.6 GHz处的最大吸收强度达到-61.4 dB;在厚度为2.5 mm时,合适的吸收带宽为10.04 - 18.00 GHz,实现了对Ku波段的全覆盖。作为制备轻质宽带电磁波吸收材料的新选择,rGO-NiMnO是一种理想的电磁波防护材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6540/9000542/c6d3a55a687e/nanomaterials-12-01089-g001.jpg

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