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锗在硅(111)表面外延生长过程中7×7到5×5超结构转变的特性

Peculiarities of the 7 × 7 to 5 × 5 Superstructure Transition during Epitaxial Growth of Germanium on Silicon (111) Surface.

作者信息

Dirko Vladimir V, Lozovoy Kirill A, Kokhanenko Andrey P, Kukenov Olzhas I, Korotaev Alexander G, Voitsekhovskii Alexander V

机构信息

Faculty of Radiophysics, National Research Tomsk State University, Lenin Av. 36, 634050 Tomsk, Russia.

出版信息

Nanomaterials (Basel). 2023 Jan 4;13(2):231. doi: 10.3390/nano13020231.

DOI:10.3390/nano13020231
PMID:36677983
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9862873/
Abstract

This paper presents the results of studying the processes of epitaxial growth of germanium on silicon with crystallographic orientation (111) in a wide temperature range. The temperature dependences of the duration of the transition stage from the 7 × 7 to 5 × 5 superstructure and the values of the critical thickness of the transition from two-dimensional to three-dimensional growth in the range from 250 to 700 °C are determined using the reflection high-energy electron diffraction method. It was shown for the first time that the transition time from the 7 × 7 superstructure to 5 × 5 superstructure depends on the temperature of epitaxial growth. The region of low temperatures of synthesis, which has received insufficient attention so far, is also considered.

摘要

本文介绍了在很宽的温度范围内,对锗在具有(111)晶体取向的硅上进行外延生长过程的研究结果。利用反射高能电子衍射方法,测定了在250至700°C范围内,从7×7超结构到5×5超结构的转变阶段持续时间的温度依赖性,以及从二维生长到三维生长转变的临界厚度值。首次表明,从7×7超结构到5×5超结构的转变时间取决于外延生长温度。还考虑了到目前为止关注不足的低温合成区域。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/7f41655640b9/nanomaterials-13-00231-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/112f0426cf62/nanomaterials-13-00231-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/16dedaf30bd8/nanomaterials-13-00231-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/67c558046cbb/nanomaterials-13-00231-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/8346ea5f16d3/nanomaterials-13-00231-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/f2dd07e145d2/nanomaterials-13-00231-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/15e3facc3e7c/nanomaterials-13-00231-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/cffa4d89766b/nanomaterials-13-00231-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/78cb531a1aeb/nanomaterials-13-00231-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/7f41655640b9/nanomaterials-13-00231-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/112f0426cf62/nanomaterials-13-00231-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/16dedaf30bd8/nanomaterials-13-00231-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/67c558046cbb/nanomaterials-13-00231-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/8346ea5f16d3/nanomaterials-13-00231-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/f2dd07e145d2/nanomaterials-13-00231-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/15e3facc3e7c/nanomaterials-13-00231-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/cffa4d89766b/nanomaterials-13-00231-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/78cb531a1aeb/nanomaterials-13-00231-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05b9/9862873/7f41655640b9/nanomaterials-13-00231-g009.jpg

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本文引用的文献

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Nanoscale Adv. 2020 Nov 19;3(4):997-1004. doi: 10.1039/d0na00680g. eCollection 2021 Feb 23.
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Single-Element 2D Materials beyond Graphene: Methods of Epitaxial Synthesis.超越石墨烯的单元素二维材料:外延合成方法
Nanomaterials (Basel). 2022 Jun 28;12(13):2221. doi: 10.3390/nano12132221.
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High-resolution RHEED analysis of dynamics of low-temperature superstructure transitions in Ge/Si(001) epitaxial system.
Ge/Si(001)外延系统中低温超结构转变动力学的高分辨率反射高能电子衍射分析
Nanotechnology. 2021 Dec 22;33(11). doi: 10.1088/1361-6528/ac3f56.
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Thickness-dependent elastic strain in Stranski-Krastanow growth.斯特兰斯基-克拉斯坦诺夫生长中与厚度相关的弹性应变。
Phys Chem Chem Phys. 2020 Sep 8;22(34):19318-19325. doi: 10.1039/d0cp03538f.
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