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毛竹热处理后化学成分变化及抗真菌性研究

Research on the Change in Chemical Composition and Fungal Resistance of Moso Bamboo with Heat Treatment.

作者信息

Yu Wangwang, Wang Yong

机构信息

School of Mechanical Engineering, Nanjing Vocational University of Industry Technology, Nanjing 210023, China.

出版信息

Polymers (Basel). 2023 Jan 15;15(2):453. doi: 10.3390/polym15020453.

DOI:10.3390/polym15020453
PMID:36679333
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9866750/
Abstract

Bamboo, as a potential alternative to biomass materials, has gained more attention from the bamboo manufacturing industry in China. However, the drawbacks, such as the dimensional instability, and low antifungal and hydrophilic properties of bamboo, inhibit its application and shorten its service life. The objective of this work was to analyze the change in chemical components and fungal resistance of moso bamboo with heat treatment. For this objective, moso bamboo specimens were thermally modified in an oven at different temperatures for a fixed duration. The results showed that the parenchymal cells distorted and deformed in comparison to the control after thermal modification. After thermal modification in an oven, the crystallinity index increased from 39% to 53%. Owing to the thermal modification, the hemicellulose and cellulose relative content decreased, as confirmed by FTIR and XPS analysis. Thus, the dimensional stability and antifungal properties of the thermally modified bamboo specimens improved.

摘要

竹子作为生物质材料的一种潜在替代品,在中国竹制品制造业中受到了更多关注。然而,竹子存在诸如尺寸不稳定、抗真菌性能低和亲水性差等缺点,这限制了其应用并缩短了其使用寿命。本研究的目的是分析毛竹经热处理后化学成分的变化和抗真菌性能。为此,将毛竹试件在烘箱中于不同温度下进行固定时长的热改性处理。结果表明,与对照相比,热改性后的薄壁细胞发生了扭曲和变形。在烘箱中进行热改性后,结晶度指数从39%提高到了53%。傅里叶变换红外光谱(FTIR)和X射线光电子能谱(XPS)分析证实,由于热改性,半纤维素和纤维素的相对含量降低。因此,热改性竹试件的尺寸稳定性和抗真菌性能得到了改善。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/4368d88251ab/polymers-15-00453-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/8788c4644cc5/polymers-15-00453-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/76bf6589a9e0/polymers-15-00453-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/f14b8df88b89/polymers-15-00453-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/11523c180831/polymers-15-00453-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/10b5ffbeb73e/polymers-15-00453-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/4368d88251ab/polymers-15-00453-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/8788c4644cc5/polymers-15-00453-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/76bf6589a9e0/polymers-15-00453-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/f14b8df88b89/polymers-15-00453-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/11523c180831/polymers-15-00453-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/10b5ffbeb73e/polymers-15-00453-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c74f/9866750/4368d88251ab/polymers-15-00453-g006.jpg

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本文引用的文献

1
Multi-Scale Evaluation of the Effect of Thermal Modification on Chemical Components, Dimensional Stability, and Anti-Mildew Properties of Moso Bamboo.热改性对毛竹化学成分、尺寸稳定性及防霉性能影响的多尺度评价
Polymers (Basel). 2022 Nov 2;14(21):4677. doi: 10.3390/polym14214677.
2
Pressure-Steam Heat Treatment-Enhanced Anti-Mildew Property of Arc-Shaped Bamboo Sheets.压力蒸汽热处理增强弧形竹板材防霉性能
Polymers (Basel). 2022 Sep 2;14(17):3644. doi: 10.3390/polym14173644.
3
Water-Induced Self-Assembly and Mineralization within Plant Phenolic Glycol-Gel toward Ultrastrong and Multifunctional Thermal Insulating Aerogels.
水诱导植物酚醛二醇凝胶内的自组装和矿化以制备超强多功能隔热气凝胶
ACS Nano. 2022 Jun 28;16(6):9062-9076. doi: 10.1021/acsnano.2c00755. Epub 2022 Jun 2.
4
Quantitative Visualization of Weak Layers in Bamboo at the Cellular and Subcellular Levels.竹子中细胞和亚细胞水平薄弱层的定量可视化
ACS Appl Bio Mater. 2020 Oct 19;3(10):7087-7094. doi: 10.1021/acsabm.0c00921. Epub 2020 Oct 5.